Collapse to view only § 68.126 - Exclusion.
- § 68.100 - Purpose.
- § 68.115 - Threshold determination.
- § 68.120 - Petition process.
- § 68.125 - Exemptions.
- § 68.126 - Exclusion.
- § 68.130 - List of substances.
§ 68.100 - Purpose.
This subpart designates substances to be listed under section 112(r)(3), (4), and (5) of the Clean Air Act, as amended, identifies their threshold quantities, and establishes the requirements for petitioning to add or delete substances from the list.
§ 68.115 - Threshold determination.
(a) A threshold quantity of a regulated substance listed in § 68.130 is present at a stationary source if the total quantity of the regulated substance contained in a process exceeds the threshold.
(b) For the purposes of determining whether more than a threshold quantity of a regulated substance is present at the stationary source, the following exemptions apply:
(1) Concentrations of a regulated toxic substance in a mixture. If a regulated substance is present in a mixture and the concentration of the substance is below one percent by weight of the mixture, the amount of the substance in the mixture need not be considered when determining whether more than a threshold quantity is present at the stationary source. Except for oleum, toluene 2,4-diisocyanate, toluene 2,6-diisocyanate, and toluene diisocyanate (unspecified isomer), if the concentration of the regulated substance in the mixture is one percent or greater by weight, but the owner or operator can demonstrate that the partial pressure of the regulated substance in the mixture (solution) under handling or storage conditions in any portion of the process is less than 10 millimeters of mercury (mm Hg), the amount of the substance in the mixture in that portion of the process need not be considered when determining whether more than a threshold quantity is present at the stationary source. The owner or operator shall document this partial pressure measurement or estimate.
(2) Concentrations of a regulated flammable substance in a mixture. (i) General provision. If a regulated substance is present in a mixture and the concentration of the substance is below one percent by weight of the mixture, the mixture need not be considered when determining whether more than a threshold quantity of the regulated substance is present at the stationary source. Except as provided in paragraph (b)(2) (ii) and (iii) of this section, if the concentration of the substance is one percent or greater by weight of the mixture, then, for purposes of determining whether a threshold quantity is present at the stationary source, the entire weight of the mixture shall be treated as the regulated substance unless the owner or operator can demonstrate that the mixture itself does not have a National Fire Protection Association flammability hazard rating of 4. The demonstration shall be in accordance with the definition of flammability hazard rating 4 in the NFPA 704, Standard System for the Identification of the Hazards of Materials for Emergency Response, National Fire Protection Association, Quincy, MA, 1996. Available from the National Fire Protection Association, 1 Batterymarch Park, Quincy, MA 02269-9101. This incorporation by reference was approved by the Director of the Federal Register in accordance with 5 U.S.C. 552(a) and 1 CFR part 51. Copies may be inspected at the Environmental Protection Agency Air Docket (6102), Attn: Docket No. A-96-O8, Waterside Mall, 401 M. St. SW., Washington DC; or at the National Archives and Records Administration (NARA). For information on the availability of this material at NARA, call 202-741-6030, or go to: http://www.archives.gov/federal_register/code_of_federal_regulations/ibr_locations.html. Boiling point and flash point shall be defined and determined in accordance with NFPA 30, Flammable and Combustible Liquids Code, National Fire Protection Association, Quincy, MA, 1996. Available from the National Fire Protection Association, 1 Batterymarch Park, Quincy, MA 02269-9101. This incorporation by reference was approved by the Director of the Federal Register in accordance with 5 U.S.C. 552(a) and 1 CFR part 51. Copies may be inspected at the Environmental Protection Agency Air Docket (6102), Attn: Docket No. A-96-O8, Waterside Mall, 401 M. St. SW., Washington DC; or at the National Archives and Records Administration (NARA). For information on the availability of this material at NARA, call 202-741-6030, or go to: http://www.archives.gov/federal_register/code_of_federal_regulations/ibr_locations.html. The owner or operator shall document the National Fire Protection Association flammability hazard rating.
(ii) Gasoline. Regulated substances in gasoline, when in distribution or related storage for use as fuel for internal combustion engines, need not be considered when determining whether more than a threshold quantity is present at a stationary source.
(iii) Naturally occurring hydrocarbon mixtures. Prior to entry into a natural gas processing plant or a petroleum refining process unit, regulated substances in naturally occurring hydrocarbon mixtures need not be considered when determining whether more than a threshold quantity is present at a stationary source. Naturally occurring hydrocarbon mixtures include any combination of the following: condensate, crude oil, field gas, and produced water, each as defined in § 68.3 of this part.
(3) Articles. Regulated substances contained in articles need not be considered when determining whether more than a threshold quantity is present at the stationary source.
(4) Uses. Regulated substances, when in use for the following purposes, need not be included in determining whether more than a threshold quantity is present at the stationary source:
(i) Use as a structural component of the stationary source;
(ii) Use of products for routine janitorial maintenance;
(iii) Use by employees of foods, drugs, cosmetics, or other personal items containing the regulated substance; and
(iv) Use of regulated substances present in process water or non-contact cooling water as drawn from the environment or municipal sources, or use of regulated substances present in air used either as compressed air or as part of combustion.
(5) Activities in laboratories. If a regulated substance is manufactured, processed, or used in a laboratory at a stationary source under the supervision of a technically qualified individual as defined in § 720.3(ee) of this chapter, the quantity of the substance need not be considered in determining whether a threshold quantity is present. This exemption does not apply to:
(i) Specialty chemical production;
(ii) Manufacture, processing, or use of substances in pilot plant scale operations; and
(iii) Activities conducted outside the laboratory.
§ 68.120 - Petition process.
(a) Any person may petition the Administrator to modify, by addition or deletion, the list of regulated substances identified in § 68.130. Based on the information presented by the petitioner, the Administrator may grant or deny a petition.
(b) A substance may be added to the list if, in the case of an accidental release, it is known to cause or may be reasonably anticipated to cause death, injury, or serious adverse effects to human health or the environment.
(c) A substance may be deleted from the list if adequate data on the health and environmental effects of the substance are available to determine that the substance, in the case of an accidental release, is not known to cause and may not be reasonably anticipated to cause death, injury, or serious adverse effects to human health or the environment.
(d) No substance for which a national primary ambient air quality standard has been established shall be added to the list. No substance regulated under title VI of the Clean Air Act, as amended, shall be added to the list.
(e) The burden of proof is on the petitioner to demonstrate that the criteria for addition and deletion are met. A petition will be denied if this demonstration is not made.
(f) The Administrator will not accept additional petitions on the same substance following publication of a final notice of the decision to grant or deny a petition, unless new data becomes available that could significantly affect the basis for the decision.
(g) Petitions to modify the list of regulated substances must contain the following:
(1) Name and address of the petitioner and a brief description of the organization(s) that the petitioner represents, if applicable;
(2) Name, address, and telephone number of a contact person for the petition;
(3) Common chemical name(s), common synonym(s), Chemical Abstracts Service number, and chemical formula and structure;
(4) Action requested (add or delete a substance);
(5) Rationale supporting the petitioner's position; that is, how the substance meets the criteria for addition and deletion. A short summary of the rationale must be submitted along with a more detailed narrative; and
(6) Supporting data; that is, the petition must include sufficient information to scientifically support the request to modify the list. Such information shall include:
(i) A list of all support documents;
(ii) Documentation of literature searches conducted, including, but not limited to, identification of the database(s) searched, the search strategy, dates covered, and printed results;
(iii) Effects data (animal, human, and environmental test data) indicating the potential for death, injury, or serious adverse human and environmental impacts from acute exposure following an accidental release; printed copies of the data sources, in English, should be provided; and
(iv) Exposure data or previous accident history data, indicating the potential for serious adverse human health or environmental effects from an accidental release. These data may include, but are not limited to, physical and chemical properties of the substance, such as vapor pressure; modeling results, including data and assumptions used and model documentation; and historical accident data, citing data sources.
(h) Within 18 months of receipt of a petition, the Administrator shall publish in the
§ 68.125 - Exemptions.
Agricultural nutrients. Ammonia used as an agricultural nutrient, when held by farmers, is exempt from all provisions of this part.
§ 68.126 - Exclusion.
Flammable Substances Used as Fuel or Held for Sale as Fuel at Retail Facilities. A flammable substance listed in Tables 3 and 4 of § 68.130 is nevertheless excluded from all provisions of this part when the substance is used as a fuel or held for sale as a fuel at a retail facility.
§ 68.130 - List of substances.
(a) Regulated toxic and flammable substances under section 112(r) of the Clean Air Act are the substances listed in Tables 1, 2, 3, and 4. Threshold quantities for listed toxic and flammable substances are specified in the tables.
(b) The basis for placing toxic and flammable substances on the list of regulated substances are explained in the notes to the list.
Table 1 to § 68.130—List of Regulated Toxic Substances and Threshold Quantities for Accidental Release Prevention
[Alphabetical Order—77 Substances]
| Chemical name | CAS No. | Threshold quantity (lbs) | Basis for listing | Acrolein [2-Propenal] | 107-02-8 | 5,000 | b | Acrylonitrile [2-Propenenitrile] | 107-13-1 | 20,000 | b | Acrylyl chloride [2-Propenoyl chloride] | 814-68-6 | 5,000 | b | Allyl alcohol [2-Propen-l-ol] | 107-18-6 | 15,000 | b | Allylamine [2-Propen-l-amine] | 107-11-9 | 10,000 | b | Ammonia (anhydrous) | 7664-41-7 | 10,000 | a, b | Ammonia (conc 20% or greater) | 7664-41-7 | 20,000 | a, b | Arsenous trichloride | 7784-34-1 | 15,000 | b | Arsine | 7784-42-1 | 1,000 | b | Boron trichloride [Borane, trichloro-] | 10294-34-5 | 5,000 | b | Boron trifluoride [Borane, trifluoro-] | 7637-07-2 | 5,000 | b | Boron trifluoride compound with methyl ether (1:1) [Boron, trifluoro [oxybis [metane]]-, T-4- | 353-42-4 | 15,000 | b | Bromine | 7726-95-6 | 10,000 | a, b | Carbon disulfide | 75-15-0 | 20,000 | b | Chlorine | 7782-50-5 | 2,500 | a, b | Chlorine dioxide [Chlorine oxide (ClO2)] | 10049-04-4 | 1,000 | c | Chloroform [Methane, trichloro-] | 67-66-3 | 20,000 | b | Chloromethyl ether [Methane, oxybis[chloro-] | 542-88-1 | 1,000 | b | Chloromethyl methyl ether [Methane, chloromethoxy-] | 107-30-2 | 5,000 | b | Crotonaldehyde [2-Butenal] | 4170-30-3 | 20,000 | b | Crotonaldehyde, (E)- [2-Butenal, (E)-] | 123-73-9 | 20,000 | b | Cyanogen chloride | 506-77-4 | 10,000 | c | Cyclohexylamine [Cyclohexanamine] | 108-91-8 | 15,000 | b | Diborane | 19287-45-7 | 2,500 | b | Dimethyldichlorosilane [Silane, dichlorodimethyl-] | 75-78-5 | 5,000 | b | 1,1-Dimethylhydrazine [Hydrazine, 1,1-dimethyl-] | 57-14-7 | 15,000 | b | Epichlorohydrin [Oxirane, (chloromethyl)-] | 106-89-8 | 20,000 | b | Ethylenediamine [1,2-Ethanediamine] | 107-15-3 | 20,000 | b | Ethyleneimine [Aziridine] | 151-56-4 | 10,000 | b | Ethylene oxide [Oxirane] | 75-21-8 | 10,000 | a, b | Fluorine | 7782-41-4 | 1,000 | b | Formaldehyde (solution) | 50-00-0 | 15,000 | b | Furan | 110-00-9 | 5,000 | b | Hydrazine | 302-01-2 | 15,000 | b | Hydrochloric acid (conc 37% or greater) | 7647-01-0 | 15,000 | d | Hydrocyanic acid | 74-90-8 | 2,500 | a, b | Hydrogen chloride (anhydrous) [Hydrochloric acid] | 7647-01-0 | 5,000 | a | Hydrogen fluoride/Hydrofluoric acid (conc 50% or greater) [Hydrofluoric acid] | 7664-39-3 | 1,000 | a, b | Hydrogen selenide | 7783-07-5 | 500 | b | Hydrogen sulfide | 7783-06-4 | 10,000 | a, b | Iron, pentacarbonyl- [Iron carbonyl (Fe(CO)5), (TB-5-11)-] | 13463-40-6 | 2,500 | b | Isobutyronitrile [Propanenitrile, 2-methyl-] | 78-82-0 | 20,000 | b | Isopropyl chloroformate [Carbonochloridic acid, 1-methylethyl ester] | 108-23-6 | 15,000 | b | Methacrylonitrile [2-Propenenitrile, 2-methyl-] | 126-98-7 | 10,000 | b | Methyl chloride [Methane, chloro-] | 74-87-3 | 10,000 | a | Methyl chloroformate [Carbonochloridic acid, methylester] | 79-22-1 | 5,000 | b | Methyl hydrazine [Hydrazine, methyl-] | 60-34-4 | 15,000 | b | Methyl isocyanate [Methane, isocyanato-] | 624-83-9 | 10,000 | a, b | Methyl mercaptan [Methanethiol] | 74-93-1 | 10,000 | b | Methyl thiocyanate [Thiocyanic acid, methyl ester] | 556-64-9 | 20,000 | b | Methyltrichlorosilane [Silane, trichloromethyl-] | 75-79-6 | 5,000 | b | Nickel carbonyl | 13463-39-3 | 1,000 | b | Nitric acid (conc 80% or greater) | 7697-37-2 | 15,000 | b | Nitric oxide [Nitrogen oxide (NO)] | 10102-43-9 | 10,000 | b | Oleum (Fuming Sulfuric acid) [Sulfuric acid, mixture with sulfur trioxide] 1 | 8014-95-7 | 10,000 | e | Peracetic acid [Ethaneperoxoic acid] | 79-21-0 | 10,000 | b | Perchloromethylmercaptan [Methanesulfenyl chloride, trichloro-] | 594-42-3 | 10,000 | b | Phosgene [Carbonic dichloride] | 75-44-5 | 500 | a, b | Phosphine | 7803-51-2 | 5,000 | b | Phosphorus oxychloride [Phosphoryl chloride] | 10025-87-3 | 5,000 | b | Phosphorus trichloride [Phosphorous trichloride] | 7719-12-2 | 15,000 | b | Piperidine | 110-89-4 | 15,000 | b | Propionitrile [Propanenitrile] | 107-12-0 | 10,000 | b | Propyl chloroformate [Carbonochloridic acid, propylester] | 109-61-5 | 15,000 | b | Propyleneimine [Aziridine, 2-methyl-] | 75-55-8 | 10,000 | b | Propylene oxide [Oxirane, methyl-] | 75-56-9 | 10,000 | b | Sulfur dioxide (anhydrous) | 7446-09-5 | 5,000 | a, b | Sulfur tetrafluoride [Sulfur fluoride (SF4), (T-4)-] | 7783-60-0 | 2,500 | b | Sulfur trioxide | 7446-11-9 | 10,000 | a, b | Tetramethyllead [Plumbane, tetramethyl-] | 75-74-1 | 10,000 | b | Tetranitromethane [Methane, tetranitro-] | 509-14-8 | 10,000 | b | Titanium tetrachloride [Titanium chloride (TiCl4) (T-4)-] | 7550-45-0 | 2,500 | b | Toluene 2,4-diisocyanate [Benzene, 2,4-diisocyanato-1-methyl-] 1 | 584-84-9 | 10,000 | a | Toluene 2,6-diisocyanate [Benzene, 1,3-diisocyanato-2-methyl-] 1 | 91-08-7 | 10,000 | a | Toluene diisocyanate (unspecified isomer) [Benzene, 1,3-diisocyanatomethyl-] 1 | 26471-62-5 | 10,000 | a | Trimethylchlorosilane [Silane, chlorotrimethyl-] | 75-77-4 | 10,000 | b | Vinyl acetate monomer [Acetic acid ethenyl ester] | 108-05-4 | 15,000 | b |
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1 The mixture exemption in § 68.115(b)(1) does not apply to the substance.
a Mandated for listing by Congress.
b On EHS list, vapor pressure 10 mmHg or greater.
c Toxic gas.
d Toxicity of hydrogen chloride, potential to release hydrogen chloride, and history of accidents.
e Toxicity of sulfur trioxide and sulfuric acid, potential to release sulfur trioxide, and history of accidents.
Table 2 to § 68.130—List of Regulated Toxic Substances and Threshold Quantities for Accidental Release Prevention
[CAS Number Order—77 Substances]
| CAS No. | Chemical name | Threshold quantity (lbs) | Basis for listing | 50-00-0 | Formaldehyde (solution) | 15,000 | b | 57-14-7 | 1,1-Dimethylhydrazine [Hydrazine, 1,1-dimethyl-] | 15,000 | b | 60-34-4 | Methyl hydrazine [Hydrazine, methyl-] | 15,000 | b | 67-66-3 | Chloroform [Methane, trichloro-] | 20,000 | b | 74-87-3 | Methyl chloride [Methane, chloro-] | 10,000 | a | 74-90-8 | Hydrocyanic acid | 2,500 | a, b | 74-93-1 | Methyl mercaptan [Methanethiol] | 10,000 | b | 75-15-0 | Carbon disulfide | 20,000 | b | 75-21-8 | Ethylene oxide [Oxirane] | 10,000 | a, b | 75-44-5 | Phosgene [Carbonic dichloride] | 500 | a, b | 75-55-8 | Propyleneimine [Aziridine, 2-methyl-] | 10,000 | b | 75-56-9 | Propylene oxide [Oxirane, methyl-] | 10,000 | b | 75-74-1 | Tetramethyllead [Plumbane, tetramethyl-] | 10,000 | b | 75-77-4 | Trimethylchlorosilane [Silane, chlorotrimethyl-] | 10,000 | b | 75-78-5 | Dimethyldichlorosilane [Silane, dichlorodimethyl-] | 5,000 | b | 75-79-6 | Methyltrichlorosilane [Silane, trichloromethyl-] | 5,000 | b | 78-82-0 | Isobutyronitrile [Propanenitrile, 2-methyl-] | 20,000 | b | 79-21-0 | Peracetic acid [Ethaneperoxoic acid] | 10,000 | b | 79-22-1 | Methyl chloroformate [Carbonochloridic acid, methylester] | 5,000 | b | 91-08-7 | Toluene 2,6-diisocyanate [Benzene, 1,3-diisocyanato-2-methyl-] 1 | 10,000 | a | 106-89-8 | Epichlorohydrin [Oxirane, (chloromethyl)-] | 20,000 | b | 107-02-8 | Acrolein [2-Propenal] | 5,000 | b | 107-11-9 | Allylamine [2-Propen-1-amine] | 10,000 | b | 107-12-0 | Propionitrile [Propanenitrile] | 10,000 | b | 107-13-1 | Acrylonitrile [2-Propenenitrile] | 20,000 | b | 107-15-3 | Ethylenediamine [1,2-Ethanediamine] | 20,000 | b | 107-18-6 | Allyl alcohol [2-Propen-1-ol] | 15,000 | b | 107-30-2 | Chloromethyl methyl ether [Methane, chloromethoxy-] | 5,000 | b | 108-05-4 | Vinyl acetate monomer [Acetic acid ethenyl ester] | 15,000 | b | 108-23-6 | Isopropyl chloroformate [Carbonochloridic acid, 1-methylethyl ester] | 15,000 | b | 108-91-8 | Cyclohexylamine [Cyclohexanamine] | 15,000 | b | 109-61-5 | Propyl chloroformate [Carbonochloridic acid, propylester] | 15,000 | b | 110-00-9 | Furan | 5,000 | b | 110-89-4 | Piperidine | 15,000 | b | 123-73-9 | Crotonaldehyde, (E)- [2-Butenal, (E)-] | 20,000 | b | 126-98-7 | Methacrylonitrile [2-Propenenitrile, 2-methyl-] | 10,000 | b | 151-56-4 | Ethyleneimine [Aziridine] | 10,000 | b | 302-01-2 | Hydrazine | 15,000 | b | 353-42-4 | Boron trifluoride compound with methyl ether (1:1) [Boron, trifluoro[oxybis[methane]]-, T-4- | 15,000 | b | 506-77-4 | Cyanogen chloride | 10,000 | c | 509-14-8 | Tetranitromethane [Methane, tetranitro-] | 10,000 | b | 542-88-1 | Chloromethyl ether [Methane, oxybis[chloro-] | 1,000 | b | 556-64-9 | Methyl thiocyanate [Thiocyanic acid, methyl ester] | 20,000 | b | 584-84-9 | Toluene 2,4-diisocyanate [Benzene, 2,4-diisocyanato-1-methyl-] 1 | 10,000 | a | 594-42-3 | Perchloromethylmercaptan [Methanesulfenyl chloride, trichloro-] | 10,000 | b | 624-83-9 | Methyl isocyanate [Methane, isocyanato-] | 10,000 | a, b | 814-68-6 | Acrylyl chloride [2-Propenoyl chloride] | 5,000 | b | 4170-30-3 | Crotonaldehyde [2-Butenal] | 20,000 | b | 7446-09-5 | Sulfur dioxide (anhydrous) | 5,000 | a, b | 7446-11-9 | Sulfur trioxide | 10,000 | a, b | 7550-45-0 | Titanium tetrachloride [Titanium chloride (TiCl4) (T-4)-] | 2,500 | b | 7637-07-2 | Boron trifluoride [Borane, trifluoro-] | 5,000 | b | 7647-01-0 | Hydrochloric acid (conc 37% or greater) | 15,000 | d | 7647-01-0 | Hydrogen chloride (anhydrous) [Hydrochloric acid] | 5,000 | a | 7664-39-3 | Hydrogen fluoride/Hydrofluoric acid (conc 50% or greater) [Hydrofluoric acid] | 1,000 | a, b | 7664-41-7 | Ammonia (anhydrous) | 10,000 | a, b | 7664-41-7 | Ammonia (conc 20% or greater) | 20,000 | a, b | 7697-37-2 | Nitric acid (conc 80% or greater) | 15,000 | b | 7719-12-2 | Phosphorus trichloride [Phosphorous trichloride] | 15,000 | b | 7726-95-6 | Bromine | 10,000 | a, b | 7782-41-4 | Fluorine | 1,000 | b | 7782-50-5 | Chlorine | 2,500 | a, b | 7783-06-4 | Hydrogen sulfide | 10,000 | a, b | 7783-07-5 | Hydrogen selenide | 500 | b | 7783-60-0 | Sulfur tetrafluoride [Sulfur fluoride (SF4), (T-4)-] | 2,500 | b | 7784-34-1 | Arsenous trichloride | 15,000 | b | 7784-42-1 | Arsine | 1,000 | b | 7803-51-2 | Phosphine | 5,000 | b | 8014-95-7 | Oleum (Fuming Sulfuric acid) [Sulfuric acid, mixture with sulfur trioxide] 1 | 10,000 | e | 10025-87-3 | Phosphorus oxychloride [Phosphoryl chloride] | 5,000 | b | 10049-04-4 | Chlorine dioxide [Chlorine oxide (ClO | 1,000 | c | 10102-43-9 | Nitric oxide [Nitrogen oxide (NO)] | 10,000 | b | 10294-34-5 | Boron trichloride [Borane, trichloro-] | 5,000 | b | 13463-39-3 | Nickel carbonyl | 1,000 | b | 13463-40-6 | Iron, pentacarbonyl- [Iron carbonyl (Fe(CO) | 2,500 | b | 19287-45-7 | Diborane | 2,500 | b | 26471-62-5 | Toluene diisocyanate (unspecified isomer) [Benzene, 1,3-diisocyanatomethyl-1] 1 | 10,000 | a |
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1 The mixture exemption in § 68.115(b)(1) does not apply to the substance.
a Mandated for listing by Congress.
b On EHS list, vapor pressure 10 mmHg or greater.
c Toxic gas.
d Toxicity of hydrogen chloride, potential to release hydrogen chloride, and history of accidents.
e Toxicity of sulfur trioxide and sulfuric acid, potential to release sulfur trioxide, and history of accidents.
Table 3 to § 68.130—List of Regulated Flammable Substances 1 and Threshold Quantities for Accidental Release Prevention
[Alphabetical Order—63 Substances]
| Chemical name | CAS No. | Threshold quantity (lbs) | Basis for listing | Acetaldehyde | 75-07-0 | 10,000 | g | Acetylene [Ethyne] | 74-86-2 | 10,000 | f | Bromotrifluorethylene [Ethene, bromotrifluoro-] | 598-73-2 | 10,000 | f | 1,3-Butadiene | 106-99-0 | 10,000 | f | Butane | 106-97-8 | 10,000 | f | 1-Butene | 106-98-9 | 10,000 | f | 2-Butene | 107-01-7 | 10,000 | f | Butene | 25167-67-3 | 10,000 | f | 2-Butene-cis | 590-18-1 | 10,000 | f | 2-Butene-trans [2-Butene, (E)] | 624-64-6 | 10,000 | f | Carbon oxysulfide [Carbon oxide sulfide (COS)] | 463-58-1 | 10,000 | f | Chlorine monoxide [Chlorine oxide] | 7791-21-1 | 10,000 | f | 2-Chloropropylene [1-Propene, 2-chloro-] | 557-98-2 | 10,000 | g | 1-Chloropropylene [1-Propene, 1-chloro-] | 590-21-6 | 10,000 | g | Cyanogen [Ethanedinitrile] | 460-19-5 | 10,000 | f | Cyclopropane | 75-19-4 | 10,000 | f | Dichlorosilane [Silane, dichloro-] | 4109-96-0 | 10,000 | f | Difluoroethane [Ethane, 1,1-difluoro-] | 75-37-6 | 10,000 | f | Dimethylamine [Methanamine, N-methyl-] | 124-40-3 | 10,000 | f | 2,2-Dimethylpropane [Propane, 2,2-dimethyl-] | 463-82-1 | 10,000 | f | Ethane | 74-84-0 | 10,000 | f | Ethyl acetylene [1-Butyne] | 107-00-6 | 10,000 | f | Ethylamine [Ethanamine] | 75-04-7 | 10,000 | f | Ethyl chloride [Ethane, chloro-] | 75-00-3 | 10,000 | f | Ethylene [Ethene] | 74-85-1 | 10,000 | f | Ethyl ether [Ethane, 1,1′-oxybis-] | 60-29-7 | 10,000 | g | Ethyl mercaptan [Ethanethiol] | 75-08-1 | 10,000 | g | Ethyl nitrite [Nitrous acid, ethyl ester] | 109-95-5 | 10,000 | f | Hydrogen | 1333-74-0 | 10,000 | f | Isobutane [Propane, 2-methyl] | 75-28-5 | 10,000 | f | Isopentane [Butane, 2-methyl-] | 78-78-4 | 10,000 | g | Isoprene [1,3-Butadinene, 2-methyl-] | 78-79-5 | 10,000 | g | Isopropylamine [2-Propanamine] | 75-31-0 | 10,000 | g | Isopropyl chloride [Propane, 2-chloro-] | 75-29-6 | 10,000 | g | Methane | 74-82-8 | 10,000 | f | Methylamine [Methanamine] | 74-89-5 | 10,000 | f | 3-Methyl-1-butene | 563-45-1 | 10,000 | f | 2-Methyl-1-butene | 563-46-2 | 10,000 | g | Methyl ether [Methane, oxybis-] | 115-10-6 | 10,000 | f | Methyl formate [Formic acid, methyl ester] | 107-31-3 | 10,000 | g | 2-Methylpropene [1-Propene, 2-methyl-] | 115-11-7 | 10,000 | f | 1,3-Pentadinene | 504-60-9 | 10,000 | f | Pentane | 109-66-0 | 10,000 | g | 1-Pentene | 109-67-1 | 10,000 | g | 2-Pentene, (E)- | 646-04-8 | 10,000 | g | 2-Pentene, (Z)- | 627-20-3 | 10,000 | g | Propadiene [1,2-Propadiene] | 463-49-0 | 10,000 | f | Propane | 74-98-6 | 10,000 | f | Propylene [1-Propene] | 115-07-1 | 10,000 | f | Propyne [1-Propyne] | 74-99-7 | 10,000 | f | Silane | 7803-62-5 | 10,000 | f | Tetrafluoroethylene [Ethene, tetrafluoro-] | 116-14-3 | 10,000 | f | Tetramethylsilane [Silane, tetramethyl-] | 75-76-3 | 10,000 | g | Trichlorosilane [Silane, trichloro-] | 10025-78-2 | 10,000 | g | Trifluorochloroethylene [Ethene, chlorotrifluoro-] | 79-38-9 | 10,000 | f | Trimethylamine [Methanamine, N,N-dimethyl-] | 75-50-3 | 10,000 | f | Vinyl acetylene [1-Buten-3-yne] | 689-97-4 | 10,000 | f | Vinyl chloride [Ethene, chloro-] | 75-01-4 | 10,000 | a, f | Vinyl ethyl ether [Ethene, ethoxy-] | 109-92-2 | 10,000 | g | Vinyl fluoride [Ethene, fluoro-] | 75-02-5 | 10,000 | f | Vinylidene chloride [Ethene, 1,1-dichloro-] | 75-35-4 | 10,000 | g | Vinylidene fluoride [Ethene, 1,1-difluoro-] | 75-38-7 | 10,000 | f | Vinyl methyl ether [Ethene, methoxy-] | 107-25-5 | 10,000 | f |
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1 A flammable substance when used as a fuel or held for sale as a fuel at a retail facility is excluded from all provisions of this part (see § 68.126).
a Mandated for listing by Congress.
f Flammable gas.
g Volatile flammable liquid.
Table 4 to § 68.130—List of Regulated Flammable Substances 1 and Threshold Quantities for Accidental Release Prevention
[CAS Number Order—63 Substances]
| CAS No. | Chemical name | Threshold quantity
(lbs) | Basis for listing | 60-29-7 | Ethyl ether [Ethane, 1,1′-oxybis-] | 10,000 | g | 74-82-8 | Methane | 10,000 | f | 74-84-0 | Ethane | 10,000 | f | 74-85-1 | Ethylene [Ethene] | 10,000 | f | 74-86-2 | Acetylene [Ethyne] | 10,000 | f | 74-89-5 | Methylamine [Methanamine] | 10,000 | f | 74-98-6 | Propane | 10,000 | f | 74-99-7 | Propyne [1-Propyne] | 10,000 | f | 75-00-3 | Ethyl chloride [Ethane, chloro-] | 10,000 | f | 75-01-4 | Vinyl chloride [Ethene, chloro-] | 10,000 | a, f | 75-02-5 | Vinyl fluoride [Ethene, fluoro-] | 10,000 | f | 75-04-7 | Ethylamine [Ethanamine] | 10,000 | f | 75-07-0 | Acetaldehyde | 10,000 | g | 75-08-1 | Ethyl mercaptan [Ethanethiol] | 10,000 | g | 75-19-4 | Cyclopropane | 10,000 | f | 75-28-5 | Isobutane [Propane, 2-methyl] | 10,000 | f | 75-29-6 | Isopropyl chloride [Propane, 2-chloro-] | 10,000 | g | 75-31-0 | Isopropylamine [2-Propanamine] | 10,000 | g | 75-35-4 | Vinylidene chloride [Ethene, 1,1-dichloro-] | 10,000 | g | 75-37-6 | Difluoroethane [Ethane, 1,1-difluoro-] | 10,000 | f | 75-38-7 | Vinylidene fluoride [Ethene, 1,1-difluoro-] | 10,000 | f | 75-50-3 | Trimethylamine [Methanamine, N, N-dimethyl-] | 10,000 | f | 75-76-3 | Tetramethylsilane [Silane, tetramethyl-] | 10,000 | g | 78-78-4 | Isopentane [Butane, 2-methyl-] | 10,000 | g | 78-79-5 | Isoprene [1,3,-Butadiene, 2-methyl-] | 10,000 | g | 79-38-9 | Trifluorochloroethylene [Ethene, chlorotrifluoro-] | 10,000 | f | 106-97-8 | Butane | 10,000 | f | 106-98-9 | 1-Butene | 10,000 | f | 106-99-0 | 1,3-Butadiene | 10,000 | f | 107-00-6 | Ethyl acetylene [1-Butyne] | 10,000 | f | 107-01-7 | 2-Butene | 10,000 | f | 107-25-5 | Vinyl methyl ether [Ethene, methoxy-] | 10,000 | f | 107-31-3 | Methyl formate [Formic acid, methyl ester] | 10,000 | g | 109-66-0 | Pentane | 10,000 | g | 109-67-1 | 1-Pentene | 10,000 | g | 109-92-2 | Vinyl ethyl ether [Ethene, ethoxy-] | 10,000 | g | 109-95-5 | Ethyl nitrite [Nitrous acid, ethyl ester] | 10,000 | f | 115-07-1 | Propylene [1-Propene] | 10,000 | f | 115-10-6 | Methyl ether [Methane, oxybis-] | 10,000 | f | 115-11-7 | 2-Methylpropene [1-Propene, 2-methyl-] | 10,000 | f | 116-14-3 | Tetrafluoroethylene [Ethene, tetrafluoro-] | 10,000 | f | 124-40-3 | Dimethylamine [Methanamine, N-methyl-] | 10,000 | f | 460-19-5 | Cyanogen [Ethanedinitrile] | 10,000 | f | 463-49-0 | Propadiene [1,2-Propadiene] | 10,000 | f | 463-58-1 | Carbon oxysulfide [Carbon oxide sulfide (COS)] | 10,000 | f | 463-82-1 | 2,2-Dimethylpropane [Propane, 2,2-dimethyl-] | 10,000 | f | 504-60-9 | 1,3-Pentadiene | 10,000 | f | 557-98-2 | 2-Chloropropylene [1-Propene, 2-chloro-] | 10,000 | g | 563-45-1 | 3-Methyl-1-butene | 10,000 | f | 563-46-2 | 2-Methyl-1-butene | 10,000 | g | 590-18-1 | 2-Butene-cis | 10,000 | f | 590-21-6 | 1-Chloropropylene [1-Propene, 1-chloro-] | 10,000 | g | 598-73-2 | Bromotrifluorethylene [Ethene, bromotrifluoro-] | 10,000 | f | 624-64-6 | 2-Butene-trans [2-Butene, (E)] | 10,000 | f | 627-20-3 | 2-Pentene, (Z)- | 10,000 | g | 646-04-8 | 2-Pentene, (E)- | 10,000 | g | 689-97-4 | Vinyl acetylene [1-Buten-3-yne] | 10,000 | f | 1333-74-0 | Hydrogen | 10,000 | f | 4109-96-0 | Dichlorosilane [Silane, dichloro-] | 10,000 | f | 7791-21-1 | Chlorine monoxide [Chlorine oxide] | 10,000 | f | 7803-62-5 | Silane | 10,000 | f | 10025-78-2 | Trichlorosilane [Silane, trichloro-] | 10,000 | g | 25167-67-3 | Butene | 10,000 | f |
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1 A flammable substance when used as a fuel or held for sale as a fuel at a retail facility is excluded from all provisions of this part (see § 68.126).
a Mandated for listing by Congress.
f Flammable gas.
g Volatile flammable liquid.