Collapse to view only § 420.94 - New source performance standards (NSPS).

§ 420.90 - Applicability; description of the acid pickling subcategory.

The provisions of this subpart are applicable to discharges and to the introduction of pollutants into publicly owned treatment works resulting from sulfuric acid, hydrochloric acid, or combination acid pickling operations.

§ 420.91 - Specialized definitions.

(a) The term sulfuric acid pickling means those operations in which steel products are immersed in sulfuric acid solutions to chemically remove oxides and scale, and those rinsing operations associated with such immersions.

(b) The term hydrochloric acid pickling means those operations in which steel products are immersed in hydrochloric acid solutions to chemically remove oxides and scale, and those rinsing operations associated with such immersions.

(c) The term combination acid pickling means those operations in which steel products are immersed in solutions of more than one acid to chemically remove scale and oxides, and those rinsing steps associated with such immersions.

(d) The term fume scrubber means those pollution control devices used to remove and clean fumes originating in pickling operations.

(e) The term batch means those pickling operations which process steel products such as coiled wire, rods, and tubes in discrete batches or bundles.

(f) The term continuous means those pickling operations which process steel products other than in discrete batches or bundles.

(g) The term acid recovery means those sulfuric acid pickling operations that include processes for recovering the unreacted acid from spent pickling acid solutions.

(h) The term acid regeneration means those hydrochloric acid pickling operations that include processes for regenerating acid from spent pickling acid solutions.

(i) The term neutralization means those acid pickling operations that do not include acid recovery or acid regeneration processes.

(j) The term spent acid solution (or spent pickle liquor) means those solutions of steel pickling acids which have been used in the pickling process and are discharged or removed therefrom.

(k) The term rod, wire and coil means those acid pickling operations that pickle rod, wire or coiled rod and wire products.

(l) The term bar, billet and bloom means those acid pickling operations that pickle bar, billet or bloom products.

(m) The term strip, sheet and plate means those acid pickling operations that pickle strip, sheet or plate products.

(n) The term pipe, tube and other means those acid pickling operations that pickle pipes, tubes or any steel product other than those included in paragraphs (k), (l) and (m) of this section.

§ 420.92 - Effluent limitations representing the degree of effluent reduction attainable by the application of the best practicable control technology currently available (BPT).

Except as provided in 40 CFR 125.30 through 125.32, any existing point source subject to this subpart must achieve the following effluent limitations representing the degree of effluent reduction attainable by the application of the best practicable control technology currently available.

(a) Sulfuric acid pickling (spent acid solutions and rinse waters)—(1) Rod, wire and coil.

Subpart I

Pollutant or pollutant property BPT effluent limitations Maximum for any 1 day Average of daily values for 30 consecutive days Kg/kkg (pounds per 1,000 lb) of product TSS0.08180.0350 O&G 10.03500.0117 Lead0.0005260.000175 Zinc0.0007010.000234 pH( 2)( 2)

1 The limitations for oil and grease shall be applicable when acid pickling wastewaters are treated with cold rolling wastewaters.

2 Within the range of 6.0 to 9.0.

(2) Bar, billet and bloom.

Subpart I

Pollutant or pollutant property BPT effluent limitations Maximum for any 1 day Average of daily values for 30 consecutive days Kg/kkg (pounds per 1,000 lb) of product TSS0.02630.0113 O&G 10.01130.00375 Lead0.0001690.0000563 Zinc0.0002250.0000751 pH( 2)( 2)

1 The limitations for oil and grease shall be applicable when acid pickling wastewaters are treated with cold rolling wastewaters.

2 Within the range of 6.0 to 9.0.

(3) Strip, sheet and plate.

Subpart I

Pollutant or pollutant property BPT effluent limitations Maximum for any 1 day Average of daily values for 30 consecutive days Kg/kkg (pounds per 1,000 lb) of product TSS0.05260.0225 O&G 10.02250.00751 Lead0.0003380.000113 Zinc0.0004510.000150 pH( 2)( 2)

1 The limitations for oil and grease shall be applicable when acid pickling wastewaters are treated with cold rolling wastewaters.

2 Within the range of 6.0 to 9.0.

(4) Pipe, tube and other products.

Subpart I

Pollutant or pollutant property BPT effluent limitations Maximum for any 1 day Average of daily values for 30 consecutive days Kg/kkg (pounds per 1,000 lb) of product TSS0.1460.0626 O&G 10.06260.0209 Lead0.0009390.000313 Zinc0.001250.000417 pH( 2)( 2)

1 The limitations for oil and grease shall be applicable when acid pickling wastewaters are treated with cold rolling wastewaters.

2 Within the range of 6.0 to 9.0.

(5) Fume scrubbers.

Subpart I

Pollutant or pollutant property BPT effluent limitations Maximum for any 1 day Average of daily values for 30 consecutive days Kilograms per day TSS5.722.45 O&G 12.450.819 Lead0.03680.0123 Zinc0.04910.0164 pH( 2)( 2)

1 The limitations for oil and grease shall be applicable when acid pickling wastewaters are treated with cold rolling wastewaters.

2 Within the range of 6.0 to 9.0.

The above limitations shall be applicable to each fume scrubber associated with a sulfuric acid pickling operation.

(b) Hydrochloric acid pickling (spent acid solutions and rinse waters)—(1) Rod, wire and coil.

Subpart I

Pollutant or pollutant property BPT effluent limitations Maximum for any 1 day Average of daily values for 30 consecutive days Kg/kkg (pounds per 1,000 lb) of product TSS0.1430.0613 O&G 10.06130.0204 Lead0.0009200.000307 Zinc0.001230.000409 pH( 2)( 2)

1 The limitations for oil and grease shall be applicable when acid pickling wastewaters are treated with cold rolling wastewaters.

2 Within the range of 6.0 to 9.0.

(2) Strip, sheet and plate.

Subpart I

Pollutant or pollutant property BPT effluent limitations Maximum for any 1 day Average of daily values for 30 consecutive days Kg/kkg (pounds per 1,000 lb) of product TSS0.08180.0350 O&G 10.03500.0117 Lead0.0005260.000175 Zinc0.0007010.000234 pH( 2)( 2)

1 The limitations for oil and grease shall be applicable when acid pickling wastewaters are treated with cold rolling wastewaters.

2 Within the range of 6.0 to 9.0.

(3) Pipe, tube and other products.

Subpart I

Pollutant or pollutant property BPT effluent limitations Maximum for any 1 day Average of daily values for 30 consecutive days Kg/kkg (pounds per 1,000 lb) of product TSS0.2980.128 O&G 10.1280.0426 Lead0.001920.000638 Zinc0.002550.000851 pH( 2)( 2)

1 The limitations for oil and grease shall be applicable when acid pickling wastewaters are treated with cold rolling wastewaters.

2 Within the range of 6.0 to 9.0.

(4) Fume scrubbers.

Subpart I

Pollutant or pollutant property BPT effluent limitations Maximum for any 1 day Average of daily values for 30 consecutive days Kilograms per day TSS5.722.45 O&G 12.450.819 Lead0.03680.0123 Zinc0.04910.0164 pH( 2)( 2)

1 The limitations for oil and grease shall be applicable when acid pickling wastewaters are treated with cold rolling wastewaters.

2 Within the range of 6.0 to 9.0.

The above limitations shall be applicable to each fume scrubber associated with a hydrochloric acid pickling operation.

(5) Acid regeneration (absorber vent scrubber).

Subpart I

Pollutant or pollutant property BPT effluent limitations Maximum for any 1 day Average of daily values for 30 consecutive days Kilograms per day TSS38.216.3 O&G 116.35.45 Lead0.2450.0819 Zinc0.3270.109 pH( 2)( 2)

1 The limitations for oil and grease shall be applicable when acid pickling wastewaters are treated with cold rolling wastewaters.

2 Within the range of 6.0 to 9.0.

The above limitations shall be applicable to the absorber vent scrubber wastewater associated with hydrochloric acid regeneration plants.

(c) Combination acid pickling (spent acid solution and rinse waters)—(1) Rod, Wire, and Coil.

Subpart I

Pollutant or pollutant property BPT effluent limitations Maximum for any 1 day Average of daily values for 30 consecutive days Kg/kkg (pounds per 1,000 lb) of product TSS0.1490.0638 O&G 10.06380.0213 Chromium0.002130.000852 Nickel0.001920.000638 pH( 2)( 2)

1 The limitations for oil and grease shall be applicable when acid pickling wastewaters are treated with cold rolling wastewaters.

2 Within the range of 6.0 to 9.0.

(2) Bar, billet, and bloom.

Subpart I

Pollutant or pollutant property BPT effluent limitations Maximum for any 1 day Average of daily values for 30 consecutive days Kg/kkg (pounds per 1,000 lb) of product TSS0.06720.0288 O&G 10.02880.00960 Chromium0.0009600.000384 Nickel0.0008640.000288 pH( 2)( 2)

1 The limitations for oil and grease shall be applicable when acid pickling wastewaters are treated with cold rolling wastewaters.

2 Within the range of 6.0 to 9.0.

(3) Strip, sheet, and plate—continuous.

Subpart I

Pollutant or pollutant property BPT effluent limitations Maximum for any 1 day Average of daily values for 30 consecutive days Kg/kkg (pounds per 1,000 lb) of product TSS0.4380.188 O&G 10.1880.0626 Chromium0.006260.00250 Nickel0.005630.00188 pH( 2)( 2)

1 The limitations for oil and grease shall be applicable when acid pickling wastewaters are treated with cold rolling wastewaters.

2 Within the range of 6.0 to 9.0.

(4) Strip, sheet and plate—batch.

Subpart I

Pollutant or pollutant property BPT effluent limitations Maximum for any 1 day Average of daily values for 30 consecutive days Kg/kkg (pounds per 1,000 lb) of product TSS0.1340.0576 O&G 10.05760.0192 Chromium0.001920.000768 Nickel0.001730.000576 pH( 2)( 2)

1 The limitations for oil and grease shall be applicable when acid pickling wastewaters are treated with cold rolling wastewaters.

2 Within the range of 6.0 to 9.0.

(5) Pipe, tube, and other products.

Subpart I

Pollutant or pollutant property BPT effluent limitations Maximum for any 1 day Average of daily values for 30 consecutive days Kg/kkg (pounds per 1,000 lb) of product TSS0.2250.0964 O&G 10.09640.0322 Chromium0.003220.00129 Nickel0.002890.000964 pH( 2)( 2)

1 The limitations for oil and grease shall be applicable when acid pickling wastewaters are treated with cold rolling wastewaters.

2 Within the range of 6.0 to 9.0.

(6) Fume scrubbers.

Subpart I

Pollutant or pollutant property BPT effluent limitations Maximum for any 1 day Average of daily values for 30 consecutive days Kilograms per day TSS5.722.45 O&G 12.450.819 Chromium0.08190.0327 Nickel0.07350.0245 pH( 2)( 2)

1 The limitations for oil and grease shall be applicable when acid pickling wastewaters are treated with cold rolling wastewaters.

2 Within the range of 6.0 to 9.0.

The above limitations shall be applicable to each fume scrubber associated with a combination acid pickling operation. [47 FR 23284, May 27, 1982; 47 FR 41739, Sept. 22, 1982, as amended at 49 FR 21030, May 17, 1984]

§ 420.93 - Effluent limitations representing the degree of effluent reduction attainable by the application of the best available technology economically achievable (BAT).

Except as provided in 40 CFR 125.30 through 125.32, any existing point source subject to this subpart must achieve the following effluent limitations representing the degree of effluent reduction attainable by the application of the best available technology economically achievable.

(a) Sulfuric acid pickling (spent acid solutions and rinse waters)—(1) Rod, wire and coil.

Subpart I

Pollutant or pollutant property BAT effluent limitations Maximum for any 1 day Average of daily values for 30 consecutive days Kg/kkg (pounds per 1,000 lb) of product Lead0.0005260.000175 Zinc0.0007010.000234

(2) Bar, billet and bloom.

Subpart I

Pollutant or pollutant property BAT effluent limitations Maximum for any 1 day Average of daily values for 30 consecutive days Kg/kkg (pounds per 1,000 lb) of product Lead0.0001690.0000563 Zinc0.0002250.0000751

(3) Strip, sheet and plate.

Subpart I

Pollutant or pollutant property BAT effluent limitations Maximum for any 1 day Average of daily values for 30 consecutive days Kg/kkg (pounds per 1,000 lb) of product Lead0.0003380.000113 Zinc0.0004510.000150

(4) Pipe, tube and other products.

Subpart I

Pollutant or pollutant property BAT effluent limitations Maximum for any 1 day Average of daily values for 30 consecutive days Kg/kkg (pounds per 1,000 lb) of product Lead0.0009390.000313 Zinc0.001250.000417

(5) Fume scrubbers.

Subpart I

Pollutant or pollutant property BAT effluent limitations Maximum for any 1 day Average of daily values for 30 consecutive days Kilograms per day Lead0.03680.0123 Zinc0.04910.0164
The above limitations shall be applicable to each fume scrubber associated with a sulfuric acid pickling operation.

(b) Hydrochloric acid pickling (spent acid solutions and rinse waters)—(1) Rod, wire and coil.

Subpart I

Pollutant or pollutant property BAT effluent limitations Maximum for any 1 day Average of daily values for 30 consecutive days Kg/kkg (pounds per 1,000 lb) of product Lead0.0009200.000307 Zinc0.001230.000409

(2) Strip, sheet and plate.

Subpart I

Pollutant or pollutant property BAT effluent limitations Maximum for any 1 day Average of daily values for 30 consecutive days Kg/kkg (pounds per 1,000 lb) of product Lead0.0005260.000175 Zinc0.0007010.000234

(3) Pipe, tube and other products.

Subpart I

Pollutant or pollutant property BAT effuent limitations Maximum for any 1 day Average of daily values for 30 consecutive days Kg/kkg (pounds per 1,000 lb) of product Lead0.001920.000638 Zinc0.002550.000851

(4) Fume scrubbers.

Subpart I

Pollutant or pollutant property BAT effuent limitations Maximum for any 1 day Average of daily values for 30 consecutive days Kilograms per day Lead0.03680.0123 Zinc0.04910.0164
The above limitations shall be applicable to each fume scrubber associated with a hydrochloric acid pickling operation.

(5) Acid regeneration (absorber vent scrubber).

Subpart I

Pollutant or pollutant property BAT effuent limitations Maximum for any 1 day Average of daily values for 30 consecutive days Kilograms per day Lead0.2450.0819 Zinc0.3270.109
The above limitations shall be applicable to the absorber vent scrubber wastewater associated with hydrochloric acid regeneration plants.

(c) Combination acid pickling (spent acid solution and rinse waters)—(1) Rod, wire, and coil.

Subpart I

Pollutant or pollutant property BAT effluent limitations Maximum for any 1 day Average of daily values for 30 consecutive days Kg/kkg (pounds per 1,000 lb) of product Chromium0.002130.000852 Nickel0.001920.000638

(2) Bar, billet, and bloom.

Subpart I

Pollutant or pollutant property BAT effluent limitations Maximum for any 1 day Average of daily values for 30 consecutive days Kg/kkg (pounds per 1,000 lb) of product Chromium0.0009600.000384 Nickel0.0008640.000288

(3) Strip, sheet, and plate—continuous.

Subpart I

Pollutant or pollutant property BAT effluent limitations Maximum for any 1 day Average of daily values for 30 consecutive days Kg/kkg (pounds per 1,000 lb) of product Chromium0.006260.00250 Nickel0.005630.00188

(4) Strip, sheet, and plate—batch.

Subpart I

Pollutant or pollutant property BAT effluent limitations Maximum for any 1 day Average of daily values for 30 consecutive days Kg/kkg (pounds per 1,000 lb) of product Chromium0.001920.000768 Nickel0.001730.000576

(5) Pipe, tube, and other products.

Subpart I

Pollutant or pollutant property BAT effluent limitations Maximum for any 1 day Average of daily values for 30 consecutive days Kg/kkg (pounds per 1,000 lb) of product Chromium0.003220.00129 Nickel0.002890.000964

(6) Fume scrubbers.

Subpart I

Pollutant or pollutant property BAT effluent limitations Maximum for any 1 day Average of daily values for 30 consecutive days Kilograms per day Chromium0.08190.0327 Nickel0.07350.0245
The above limitations shall be applicable to each fume scrubber associated with a combination acid pickling operation. [47 FR 23284, May 27, 1982; 47 FR 41739, Sept. 22, 1982, as amended at 49 FR 21031, May 17, 1984; 49 FR 24726, June 15, 1984]

§ 420.94 - New source performance standards (NSPS).

The discharge of wastewater pollutants from any new source subject to this subpart shall not exceed the standards set forth below.

(a) Sulfuric acid pickling (spent acid solutions and rinse waters)—(1) Rod, wire, and coil.

Subpart I

Pollutant or pollutant property New source performance standards Maximum for any 1 day Average of daily values for 30 consecutive days kg/kkg (pounds per 1,000 lb) of product TSS0.01460.00626 O&G*0.006260.00209 Lead0.00009390.0000313 Zinc0.0001250.0000417 pH( 1)( 1)

*The limitations for oil and grease shall be applicable when acid pickling wastewaters are treated with cold rolling wastewaters.

1 Within the range of 6.0 to 9.0.

(2) Bar, billet, and bloom.

Subpart I

Pollutant or pollutant property New source performance standards Maximum for any 1 day Average of daily values for 30 consecutive days kg/kkg (pounds per 1,000 lb) of product TSS0.008760.00376 O&G*0.003760.00125 Lead0.00005630.0000188 Zinc0.00007510.0000250 pH( 1)( 1)

*The limitations for oil and grease shall be applicable when acid pickling wastewaters are treated with cold rolling wastewaters.

1 Within the range of 6.0 to 9.0.

(3) Strip, sheet, and plate.

Subpart I

Pollutant or pollutant property New source performance standards Maximum for any 1 day Average of daily values for 30 consecutive days Kg/kkg (pounds per 1,000 lb) of product TSS0.01170.00501 O&G 10.005010.00167 Lead0.00007510.0000250 Zinc0.0001000.0000334 pH( 2)( 2)

1 The limitations for oil and grease shall be applicable when acid pickling wastewaters are treated with cold rolling wastewaters.

2 Within the range of 6.0 to 9.0.

(4) Pipe, tube and other products.

Subpart I

Pollutant or pollutant property New source performance standars Maximum for any 1 day Average of daily values for 30 consecutive days Kg/kkg (pounds per 1,000 lb) of product TSS0.02040.00876 O&G 10.008760.00292 Lead0.0001310.0000438 Zinc0.0001750.0000584 pH( 2)( 2)

1 The limitations for oil and grease shall be applicable when acid pickling wastewaters are treated with cold rolling wastewaters.

2 Within the range of 6.0 to 9.0.

(5) Fume scrubbers.

Subpart I

Pollutant or pollutant property New source performance standars Maximum for any 1 day Average of daily values for 30 consecutive days Kilograms per day TSS5.722.45 O&G 12.450.819 Lead0.03680.0123 Zinc0.04910.0164 pH( 2)( 2)

1 The limitations for oil and grease shall be applicable when acid pickling wastewaters are treated with cold rolling wastewaters.

2 Within the range of 6.0 to 9.0.

The above limitations shall be applicable to each fume scrubber associated with a sulfuric acid pickling operation.

(b) Hydrochloric acid pickling (spent acid solutions and rinse waters)—(1) Rod, wire, and coil.

Subpart I

Pollutant or pollutant property New source performance standards Maximum for any 1 day Average of daily values for 30 consecutive days Kg/kkg (pounds per 1,000 lb) of product TSS0.01750.00751 O&G 10.007510.00250 Lead0.0001130.0000376 Zinc0.0001500.0000501 pH( 2)( 2)

1 The limitations for oil and grease shall be applicable when acid pickling wastewaters are treated with cold rolling wastewaters.

2 Within the range of 6.0 to 9.0.

(2) Strip, sheet, and plate.

Subpart I

Pollutant or pollutant property New source performance standards Maximum for any 1 day Average of daily values for 30 consecutive days Kg/kkg (pounds per 1,000 lb) of product TSS0.01170.00501 O&G 10.005010.00167 Lead0.00007510.0000250 Zinc0.0001000.0000334 pH( 2)( 2)

1 The limitations for oil and grease shall be applicable when acid pickling wastewaters are treated with cold rolling wastewaters.

1 Within the range of 6.0 to 9.0.

(3) Pipe, tube, and other products.

Subpart I

Pollutant or pollutant property New source performance standards Maximum for any 1 day Average of daily values for 30 consecutive days Kg/kkg (pounds per 1,000 lb) of product TSS0.03210.0138 O&G 10.01380.00459 Lead0.0002060.0000688 Zinc0.0002750.0000918 pH( 2)( 2)

1 The limitations for oil and grease shall be applicable when acid pickling wastewaters are treated with cold rolling wastewaters.

2 Within the range of 6.0 to 9.0.

(4) Fume scrubbers.

Subpart I

Pollutant or pollutant property New source performance standards Maximum for any 1 day Average of daily values for 30 consecutive days Kilograms per day TSS5.722.45 O&G 12.450.819 Lead0.03680.0123 Zinc0.04910.0164 pH( 2)( 2)

1 The limitations for oil and grease shall be applicable when acid pickling wastewaters are treated with cold rolling wastewaters.

2 Within the range of 6.0 to 9.0.

The above limitations shall be applicable to each fume scrubber associated with a hydrochloric acid pickling operation.

(c) Combination acid pickling (spent acid solutions and rinse waters)—(1) Rod, wire, and coil.

Subpart I

Pollutant or pollutant property New source performance standards Maximum for any 1 day Average of daily values for 30 consecutive days kg/kkg (pounds per 1,000 lb) of product TSS0.02040.00876 O&G 10.008760.00292 Chromium0.0002920.000117 Nickel0.0002630.0000876 pH( 2)( 2)

1 The limitations for oil and grease shall be applicable when acid pickling wastewaters are treated with cold rolling wastewaters.

2 Within the range of 6.0 to 9.0.

(2) Bar, billet, and bloom.

Subpart I

Pollutant or pollutant property New source performance standards Maximum for any 1 day Average of daily values for 30 consecutive days kg/kkg (pounds per 1,000 lb) of product TSS0.01170.00501 O&G 10.005010.00167 Chromium0.0001670.0000667 Nickel0.0001500.0000501 pH( 2)( 2)

1 The limitations for oil and grease shall be applicable when acid pickling wastewaters are treated with cold rolling wastewaters.

2 Within the range of 6.0 to 9.0.

(3) Strip, sheet and plate—continuous.

Subpart I

Pollutant or pollutant property New source performance standards Maximum for any 1 day Average of daily values for 30 consecutive days Kg/kkg (pounds per 1,000 lb) of product TSS0.04960.0213 O&G 10.02130.00710 Chromium0.0007100.000284 Nickel0.0006380.000213 pH( 2)( 2)

1 The limitations for oil and grease shall be applicable when acid pickling wastewaters are treated with cold rolling wastewaters.

2 Within the range of 6.0 to 9.0.

(4) Strip, sheet, and plate—batch.

Subpart I

Pollutant or pollutant property New source performance standards Maximum for any 1 day Average of daily values for 30 consecutive days Kg/kkg (pounds per 1,000 lb) of product TSS0.01750.00751 O&G 10.007510.00250 Chromium0.0002500.000100 Nickel0.0002250.0000751 pH( 2)( 2)

1 The limitations for oil and grease shall be applicable when acid pickling wastewaters are treated with cold rolling wastewaters.

2 Within the range of 6.0 to 9.0.

(5) Pipe, tube, and other products.

Subpart I

Pollutant or pollutant property New source performance standards Maximum for any 1 day Average of daily values for 30 consecutive days Kg/kkg (pounds per 1,000 lb) of product TSS0.02920.0125 O&G 10.01250.00418 Chromium0.0004180.000167 Nickel0.0003760.000125 pH( 2)( 2)

1 The limitations for oil and grease shall be applicable when acid pickling wastewaters are treated with cold rolling wastewaters.

2 Within the range of 6.0 to 9.0.

(6) Fume scrubbers.

Subpart I

Pollutant or pollutant property New source performance standards Maximum for any 1 day Average of daily values for 30 consecutive days Kilograms per day TSS5.722.45 O&G 12.450.819 Chromium0.08190.0327 Nickel0.07350.0245 pH( 2)( 2)

1 The limitations for oil and grease shall be applicable when acid pickling wastewaters are treated with cold rolling wastewaters.

2 Within the range of 6.0 to 9.0.

The above limitations shall be applicable to each fume scrubber associated with a combination acid pickling operation. [47 FR 23284, May 27, 1982, as amended at 49 FR 21032, May 17, 1984]

§ 420.95 - Pretreatment standards for existing sources (PSES).

Except as provided in 40 CFR 403.7 and 403.13, any existing source subject to this subpart which introduces pollutants into a publicly owned treatment works must comply with 40 CFR part 403 and achieve the following pretreatment standards for existing sources.

(a) Sulfuric acid (spent acid solutions and rinse waters)—(1) Rod, wire, and coil.

Subpart I

Pollutant or pollutant property Pretreatment standards for existing sources Maximum for any 1 day Average of daily values for 30 consecutive days Kg/kkg (pounds per 1,000 lb) of product Lead0.0005260.000175 Zinc0.0007010.000234

(2) Bar, billet, and bloom.

Subpart I

Pollutant or pollutant property Pretreatment standards for existing sources Maximum for any 1 day Average of daily values for 30 consecutive days Kg/kkg (pounds per 1,000 lb) of product Lead0.0001690.0000563 Zinc0.0002250.0000751

(3) Strip, sheet, and plate.

Subpart I

Pollutant or pollutant property Pretreatment standards for existing sources Maximum for any 1 day Average of daily values for 30 consecutive days Kg/kkg (pounds per 1,000 lb) of product Lead0.0003380.000113 Zinc0.0004510.000150

(4) Pipe, tube, and other products.

Subpart I

Pollutant or pollutant property Pretreatment standards for existing sources Maximum for any 1 day Average of daily values for 30 consecutive days Kg/kkg (pounds per 1,000 lb) of product Lead0.0009390.000313 Zinc0.001250.000417

(5) Fume scrubber.

Subpart I

Pollutant or pollutant property Pretreatment standards for existing sources Maximum for any 1 day Average of daily values for 30 consecutive days Kilograms per day Lead0.03680.0123 Zinc0.04910.0164

Note: The above limitations are applicable to each fume scrubber associated with sulfuric acid pickling operations.

(b) Hydrochloric acid pickling (spent acid solutions and rinse waters)—(1) Rod, wire, and coil.

Subpart I

Pollutant or pollutant property Pretreatment standards for existing sources Maximum for any 1 day Average of daily values for 30 consecutive days Kg/kkg (pounds per 1,000 lb) of product Lead0.0009200.000307 Zinc0.001230.000409

(2) Strip, sheet, and plate.

Subpart I

Pollutant or pollutant property Pretreatment standards for existing sources Maximum for any 1 day Average of daily values for 30 consecutive days Kg/kkg (pounds per 1,000 lb) of product Lead0.0005260.000175 Zinc0.0007010.000234

(3) Pipe, tube, and other products.

Subpart I

Pollutant or pollutant property Pretreatment standards for existing sources Maximum for any 1 day Average of daily values for 30 consecutive days Kg/kkg (pounds per 1,000 lb) of product Lead0.001920.000638 Zinc0.002550.000851

(4) Fume scrubber.

Subpart I

Pollutant or pollutant property Pretreatment standards for existing sources Maximum for any 1 day Average of daily values for 30 consecutive days Kilograms per day Lead0.03680.0123 Zinc0.04910.0164

Note: The above limitations shall be applicable for each fume scrubber associated with hydrochloric acid pickling operations.

(5) Acid regeneration (absorber vent scrubber).

Subpart I

Pollutant or pollutant property Pretreatment standards for existing sources Maximum for any 1 day Average of daily values for 30 consecutive days Kilograms per day Lead0.2450.0819 Zinc0.3270.109

Note: The above limitations shall be applicable to the absorber vent scrubber wastewater associated with hydrochloric acid regeneration plants.

(c) Combination acid pickling (spent acid solutions and rinse waters)—(1) Rod, wire, and coil.

Subpart I

Pollutant or pollutant property Pretreatment standards for existing sources Maximum for any 1 day Average of daily values for 30 consecutive days Kg/kkg (pounds per 1,000 lb) of product Chromium0.002130.000852 Nickel0.001920.000638

(2) Bar, billet, and bloom.

Subpart I

Pollutant or pollutant property Pretreatment standards for existing sources Maximum for any 1 day Average of daily values for 30 consecutive days Kg/kkg (pounds per 1,000 lb) of product Chromium0.0009600.000384 Nickel0.0008640.000288

(3) Strip, sheet, and plate—continuous.

Subpart I

Pollutant or pollutant property Pretreatment standards for existing sources Maximum for any 1 day Average of daily values for 30 consecutive days Kg/kkg (pounds per 1,000 lb) of product Chromium0.006260.00250 Nickel0.005630.00188

(4) Strip, sheet, and plate—batch.

Subpart I

Pollutant or pollutant property Pretreatment standards for existing sources Maximum for any 1 day Average of daily values for 30 consecutive days Kg/kkg (pounds per 1,000 lb) of product Chromium0.001920.000768 Nickel0.001730.000576

(5) Pipe, tube, and other products.

Subpart I

Pollutant or pollutant property Pretreatment standards for existing sources Maximum for any 1 day Average of daily values for 30 consecutive days Kg/kkg (pounds per 1,000 lb) of product Chromium0.003220.00129 Nickel0.002890.000964

(6) Fume scrubber.

Subpart I

Pollutant or pollutant property Pretreatment standards for existing sources Maximum for any 1 day Average of daily values for 30 consecutive days Kilograms per day Chromium0.08190.0327 Nickel0.07350.0245

Note: The above limitations shall be applicable to each fume scrubber associated with a combination acid pickling operation.

[47 FR 23284, May 27, 1982; 47 FR 41739, Sept. 22, 1982, as amended at 49 FR 21033, May 17, 1984]

§ 420.96 - Pretreatment standards for new sources (PSNS).

Except as provided in 40 CFR 403.7, any new source subject to this subpart which introduces pollutants into a publicly owned treatment works must comply with 40 CFR part 403 and achieve the following pretreatment standards for new sources.

(a) Sulfuric acid pickling (spent acid solutions and rinse waters)—(1) Rod, wire, coil.

Subpart I

Pollutant or pollutant property Pretreatment standards for new sources Maximum for any 1 day Average of daily values for 30 consecutive days Kg/kkg (pounds per 1,000 lb) of product Lead0.00009390.0000313 Zinc0.0001250.0000417

(2) Bar, billet, and bloom.

Subpart I

Pollutant or pollutant property Pretreatment standards for new sources Maximum for any 1 day Average of daily values for 30 consecutive days Kg/kkg (pounds per 1,000 lb) of product Lead0.00005630.0000188 Zinc0.00007510.0000250

(3) Strip, sheet, and plate.

Subpart I

Pollutant or pollutant property Pretreatment standards for new sources Maximum for any 1 day Average of daily values for 30 consecutive days Kg/kkg (pounds per 1,000 lb) of product Lead0.00007510.0000250 Zinc0.0001000.0000334

(4) Pipe, tube, other products.

Subpart I

Pollutant or pollutant property Pretreatment standards for new sources Maximum for any 1 day Average of daily values for 30 consecutive days Kg/kkg (pounds per 1,000 lb) of product Lead0.0001310.0000438 Zinc0.0001750.0000584

(5) Fume scrubber.

Subpart I

Pollutant or pollutant property Pretreatment standards for new sources Maximum for any 1 day Average of daily values for 30 consecutive days Kilograms per day Lead0.03680.0123 Zinc0.04910.0164

Note: The above limitations are applicable to each fume scrubber associated with sulfuric acid pickling operations.

(b) Hydrochloric acid pickling (spent acid solutions and rinse waters)—(1) Rod, wire, coil.

Subpart I

Pollutant or pollutant property Pretreatment standards for new sources Maximum for any 1 day Average of daily values for 30 consecutive days Kg/kkg (pounds per 1,000 lb) of product Lead0.0001130.0000376 Zinc0.0001500.0000501

(2) Strip, sheet, and plate.

Subpart I

Pollutant or pollutant property Pretreatment standards for new sources Maximum for any 1 day Average of daily values for 30 consecutive days Kg/kkg (pounds per 1,000 lb) of product Lead0.00007510.0000250 Zinc0.0001000.0000334

(3) Pipe, tube, and other products.

Subpart I

Pollutant or pollutant property Pretreatment standards for new sources Maximum for any 1 day Average of daily values for 30 consecutive days Kg/kkg (pounds per 1,000 lb) of product Lead0.0002060.0000688 Zinc0.0002750.0000918

(4) Fume scrubber.

Subpart I

Pollutant or pollutant property Pretreatment standards for new sources Maximum for any 1 day Average of daily values for 30 consecutive days Kilograms per day Lead0.03680.0123 Zinc0.04910.0164

Note: The above limitations shall be applicable for each fume scrubber associated with hydrochloric acid pickling operations.

(c) Combination acid pickling (spent acid solutions and rinse waters)—(1) Rod, wire, and coil.

Subpart I

Pollutant or pollutant property Pretreatment standards for new sources Maximum for any 1 day Average of daily values for 30 consecutive days kg/kkg (pounds per 1,000 lb) of product Chromium0.0002920.000117 Nickel0.0002630.0000876

(2) Bar, billet, and bloom.

Subpart I

Pollutant or pollutant property Pretreatment standards for new sources Maximum for any 1 day Average of daily values for 30 consecutive days kg/kkg (pounds per 1,000 lb) of product Chromium0.0001670.0000667 Nickel0.0001500.0000501

(3) Strip, sheet, and plate—continuous.

Subpart I

Pollutant or pollutant property Pretreatment standards for new sources Maximum for any 1 day Average of daily values for 30 consecutive days kg/kkg (pounds per 1,000 lb) of product Chromium0.0007100.000284 Nickel0.0006380.000213

(4) Strip, sheet, and plate—batch.

Subpart I

Pollutant or pollutant property Pretreatment standards for new sources Maximum for any 1 day Average of daily values for 30 consecutive days kg/kkg (pounds per 1,000 lb) of product Chromium0.0002500.000100 Nickel0.0002250.0000751

(5) Pipe, tube, and other products.

Subpart I

Pollutant or pollutant property Pretreatment standards for new sources Maximum for any 1 day Average of daily values for 30 consecutive days Kg/kkg (pounds per 1,000 lb) of product Chromium0.0004180.000167 Nickel0.0003760.000125

(6) Fume scrubber.

Subpart I

Pollutant or pollutant property Pretreatment standards for new sources Maximum for any 1 day Average of daily values for 30 consecutive days Kilograms per day Chromium0.08190.0327 Nickel0.07350.0245

Note: The above limitations shall be applicable for each fume scrubber associated with combination acid pickling operations.

[47 FR 23284, May 27, 1982, as amended at 47 FR 41739, Sept. 22, 1982; 49 FR 21033, May 17, 1984]

§ 420.97 - Effluent limitations representing the degree of effluent reduction attainable by the application of the best conventional technology (BCT).

Except as provided in 40 CFR 125.30 through 125.32, any existing point source subject to this subpart must achieve the following effluent limitations representing the degree of effluent reduction attainable by the application of the best conventional technology.

(a) Sulfuric acid pickling (spent acid solutions and rinse waters)—(1) Rod, wire and coil.

Subpart I

Pollutant or pollutant property BCT effluent limitations Maximum for any 1 day Average of daily values for 30 consecutive days Kg/kkg (pounds per 1,000 lb) of product TSS0.08190.0350 O&G 10.03500.0117 pH( 2)( 2)

1 The limitations for oil and grease shall be applicable when acid pickling wastewaters are treated with cold rolling wastewaters.

2 Within the range of 6.0 to 9.0.

(2) Bar, billet and bloom.

Subpart I

Pollutant or pollutant property BCT effluent limitations Maximum for any 1 day Average of daily values for 30 consecutive days Kg/kkg (pounds per 1,000 lb) of product TSS0.02630.0113 O&G 10.01130.00376 pH( 2)( 2)

1 The limitations for oil and grease shall be applicable when acid pickling wastewaters are treated with cold rolling wastewaters.

2 Within the range of 6.0 to 9.0.

(3) Strip, sheet and plate.

Subpart I

Pollutant or pollutant property BCT effluent limitations Maximum for any 1 day Average of daily values for 30 consecutive days Kg/kkg (pounds per 1,000 lb) of product TSS0.05260.0225 O&G 10.02250.00751 pH( 2)( 2)

1 The limitations for oil and grease shall be applicable when acid pickling wastewaters are treated with cold rolling wastewaters.

2 Within the range of 6.0 to 9.0.

(4) Pipe, tube and other products.

Subpart I

Pollutant or pollutant property BCT effluent limitations Maximum for any 1 day Average of daily values for 30 consecutive days Kg/kkg (pounds per 1,000 lb) of product TSS0.1460.0626 O&G 10.06260.0209 pH( 2)( 2)

1 The limitations for oil and grease shall be applicable when acid pickling wastewaters are treated with cold rolling wastewaters.

2 Within the range of 6.0 to 9.0.

(5) Fume scrubbers.

Subpart I

Pollutant or pollutant property BCT effluent limitations Maximum for any 1 day Average of daily values for 30 consecutive days Kilograms per day TSS5.722.45 O&G 12.450.819 pH( 2)( 2)

1 The limitations for oil and grease shall be applicable when acid pickling wastewaters are treated with cold rolling wastewaters.

2 Within the range of 6.0 to 9.0.

The above limitations shall be applicable to each fume scrubber associated with a sulfuric acid pickling operation.

(b) Hydrochloric acid pickling (spent acid solutions and rinse waters)—(1) Rod, wire and coil.

Subpart I

Pollutant or pollutant property BCT effluent limitations Maximum for any 1 day Average of daily values for 30 consecutive days Kg/kkg (pounds per 1,000 lb) of product TSS0.1430.0613 O&G 10.06130.0204 pH( 2)( 2)

1 The limitations for oil and grease shall be applicable when acid pickling wastewaters are treated with cold rolling wastewaters.

2 Within the range of 6.0 to 9.0.

(2) Strip, sheet and plate.

Subpart I

Pollutant or pollutant property BCT effluent limitations Maximum for any 1 day Average of daily values for 30 consecutive days Kg/kkg (pounds per 1,000 lb) of product TSS0.08190.0350 O&G 10.03500.0117 pH( 2)( 2)

1 The limitations for oil and grease shall be applicable when acid pickling wastewaters are treated with cold rolling wastewaters.

2 Within the range of 6.0 to 9.0.

(3) Pipe, tube and other products.

Subpart I

Pollutant or pollutant property BCT effluent limitations Maximum for any 1 day Average of daily values for 30 consecutive days Kg/kkg (pounds per 1,000 lb) of product TSS0.2980.128 O&G 10.1280.0426 pH( 2)( 2)

1 The limitations for oil and grease shall be applicable when acid pickling wastewaters are treated with cold rolling wastewaters.

2 Within the range of 6.0 to 9.0

(4) Fume scrubbers.

Subpart I

Pollutant or pollutant property BCT effluent limitations Maximum for any 1 day Average of daily values for 30 consecutive days Kilograms per day TSS5.722.45 O&G 12.450.819 pH( 2)( 2)

1 The limitations for oil and grease shall be applicable when acid pickling wastewaters are treated with cold rolling wastewaters.

2 Within the range of 6.0 to 9.0.

The above limitations shall be applicable to each fume scrubber associated with a hydrochloric acid pickling operation.

(5) Acid regeneration (absorber vent scrubber).

Subpart I

Pollutant or pollutant property BCT effluent limitations Maximum for any 1 day Average of daily values for 30 consecutive days Kilograms per day TSS38.216.3 O&G 116.35.45 pH( 2)( 2)

1 The limitations for oil and grease shall be applicable when acid pickling wastewaters are treated with cold rolling wastewaters.

2 Within the range of 6.0 to 9.0.

The above limitations shall be applicable to the absorber vent scrubber wastewater associated with hydrochloric acid regeneration plants.

(c) Combination acid pickling (spent acid solution and rinse waters)—(1) Rod, wire, and coil.

Subpart I

Pollutant or pollutant property BCT effluent limitations Maximum for any 1 day Average of daily values for 30 consecutive days Kg/kkg (pounds per 1,000 lb) of product TSS0.1490.0638 O&G 10.06380.0213 pH( 2)( 2)

1 The limitations for oil and grease shall be applicable when acid pickling wastewaters are treated with cold rolling wastewaters.

2 Within the range of 6.0 to 9.0.

(2) Bar, billet, and bloom.

Subpart I

Pollutant or pollutant property BCT effluent limitations Maximum for any 1 day Average of daily values for 30 consecutive days Kg/kkg (pounds per 1,000 lb) of product TSS0.06720.0288 O&G 10.02880.00960 pH( 2)( 2)

1 The limitations for oil and grease shall be applicable when acid pickling wastewaters are treated with cold rolling wastewaters.

2 Within the range of 6.0 to 9.0.

(3) Strip, sheet, and plate—continuous.

Subpart I

Pollutant or pollutant property BCT effluent limitations Maximum for any 1 day Average of daily values for 30 consecutive days Kg/kkg (pounds per 1,000 lb) of product TSS0.4380.188 O&G 10.1880.0626 pH( 2)( 2)

1 The limitations for oil and grease shall be applicable when acid pickling wastewaters are treated with cold rolling wastewaters.

2 Within the range of 6.0 to 9.0.

(4) Strip, sheet and plate—batch.

Subpart I

Pollutant or pollutant property BCT effluent limitations Maximum for any 1 day Average of daily values for 30 consecutive days Kg/kkg (pounds per 1,000 lb) of product TSS0.1340.0576 O&G 10.05760.0192 pH( 2)( 2)

1 The limitations for oil and grease shall be applicable when acid pickling wastewaters are treated with cold rolling wastewaters.

2 Within the range of 6.0 to 9.0.

(5) Pipe, tube, and other products.

Subpart I

Pollutant or pollutant property BCT effluent limitations Maximum for any 1 day Average of daily values for 30 consecutive days Kg/kkg (pounds per 1,000 lb) of product TSS0.2250.0964 O&G 10.09640.0321 pH( 2)( 2)

1 The limitations for oil and grease shall be applicable when acid pickling wastewaters are treated with cold rolling wastewaters.

2 Within the range of 6.0 to 9.0.

(6) Fume scrubbers.

Subpart I

Pollutant or pollutant property BCT effluent limitations Maximum for any 1 day Average of daily values for 30 consecutive days Kilograms per day TSS5.722.45 O&G 12.450.819 pH( 2)( 2)

1 The limitations for oil and grease shall be applicable when acid pickling wastewaters are treated with cold rolling wastewaters.

2 Within the range of 6.0 to 9.0.

The above limitations shall be applicable to each fume scrubber associated with a combination acid pickling operation. [47 FR 23284, May 27, 1982; 47 FR 41739, Sept. 22, 1982]