Collapse to view only § 60.660 - Applicability and designation of affected facility.
- § 60.660 - Applicability and designation of affected facility.
- § 60.661 - Definitions.
- § 60.662 - Standards.
- § 60.663 - Monitoring of emissions and operations.
- § 60.664 - Test methods and procedures.
- § 60.665 - Reporting and recordkeeping requirements.
- § 60.666 - Reconstruction.
- § 60.667 - Chemicals affected by subpart NNN.
- § 60.668 - Delegation of authority.
§ 60.660 - Applicability and designation of affected facility.
(a) The provisions of this subpart apply to each affected facility designated in paragraph (b) of this section that is part of a process unit that produces any of the chemicals listed in § 60.667 as a product, co-product, by-product, or intermediate, except as provided in paragraph (c).
(b) The affected facility is any of the following for which construction, modification, or reconstruction commenced after December 30, 1983:
(1) Each distillation unit not discharging its vent stream into a recovery system.
(2) Each combination of a distillation unit and the recovery system into which its vent stream is discharged.
(3) Each combination of two or more distillation units and the common recovery system into which their vent streams are discharged.
(c) Exemptions from the provisions of paragraph (a) of this section are as follows:
(1) Any distillation unit operating as part of a process unit which produces coal tar or beverage alcohols, or which uses, contains, and produces no VOC is not an affected facility.
(2) Any distillation unit that is subject to the provisions of subpart DDD is not an affected facility.
(3) Any distillation unit that is designed and operated as a batch operation is not an affected facility.
(4) Each affected facility that has a total resource effectiveness (TRE) index value greater than 8.0 is exempt from all provisions of this subpart except for §§ 60.662; 60.664 (e), (f), and (g); and 60.665 (h) and (l).
(5) Each affected facility in a process unit with a total design capacity for all chemicals produced within that unit of less than one gigagram per year is exempt from all provisions of this subpart except for the recordkeeping and reporting requirements in paragraphs (j), (l)(6), and (n) of § 60.665.
(6) Each affected facility operated with a vent stream flow rate less than 0.008 scm/min is exempt from all provisions of this subpart except for the test method and procedure and the recordkeeping and reporting requirements in § 60.664(g) and paragraphs (i), (l)(5), and (o) of § 60.665.
(d) Alternative means of compliance—(1) Option to comply with part 65. Owners or operators of process vents that are subject to this subpart may choose to comply with the provisions of 40 CFR part 65, subpart D, to satisfy the requirements of §§ 60.662 through 60.665 and 60.668. The provisions of 40 CFR part 65 also satisfy the criteria of paragraphs (c)(4) and (6) of this section. Other provisions applying to an owner or operator who chooses to comply with 40 CFR part 65 are provided in 40 CFR 65.1.
(2) Part 60, subpart A. Owners or operators who choose to comply with 40 CFR part 65, subpart D, must also comply with §§ 60.1, 60.2, 60.5, 60.6, 60.7(a)(1) and (4), 60.14, 60.15, and 60.16 for those process vents. All sections and paragraphs of subpart A of this part that are not mentioned in this paragraph (d)(2) do not apply to owners or operators of process vents complying with 40 CFR part 65, subpart D, except that provisions required to be met prior to implementing 40 CFR part 65 still apply. Owners and operators who choose to comply with 40 CFR part 65, subpart D, must comply with 40 CFR part 65, subpart A.
(3) Compliance date. Owners or operators who choose to comply with 40 CFR part 65, subpart D, at initial startup shall comply with paragraphs (d)(1) and (2) of this section for each vent stream on and after the date on which the initial performance test is completed, but not later than 60 days after achieving the maximum production rate at which the affected facility will be operated, or 180 days after the initial startup, whichever date comes first.
(4) Initial startup notification. Each owner or operator subject to the provisions of this subpart that chooses to comply with 40 CFR part 65, subpart D, at initial startup shall notify the Administrator of the specific provisions of 40 CFR 65.63(a)(1), (2), or (3), with which the owner or operator has elected to comply. Notification shall be submitted with the notifications of initial startup required by 40 CFR 65.5(b).
Note:The intent of these standards is to minimize the emissions of VOC through the application of best demonstrated technology (BDT). The numerical emission limits in these standards are expressed in terms of total organic compounds (TOC), measured as TOC less methane and ethane. This emission limit reflects the performance of BDT.
§ 60.661 - Definitions.
As used in this subpart, all terms not defined here shall have the meaning given them in the Act and in subpart A of part 60, and the following terms shall have the specific meanings given them.
Batch distillation operation means a noncontinuous distillation operation in which a discrete quantity or batch of liquid feed is charged into a distillation unit and distilled at one time. After the initial charging of the liquid feed, no additional liquid is added during the distillation operation.
Boiler means any enclosed combustion device that extracts useful energy in the form of steam.
By compound means by individual stream components, not carbon equivalents.
Continuous recorder means a data recording device recording an instantaneous data value at least once every 15 minutes.
Distillation operation means an operation separating one or more feed stream(s) into two or more exit stream(s), each exit stream having component concentrations different from those in the feed stream(s). The separation is achieved by the redistribution of the components between the liquid and vapor-phase as they approach equilibrium within the distillation unit.
Distillation unit means a device or vessel in which distillation operations occur, including all associated internals (such as trays or packing) and accessories (such as reboiler, condenser, vacuum pump, steam jet, etc.), plus any associated recovery system.
Flame zone means the portion of the combustion chamber in a boiler occupied by the flame envelope.
Flow indicator means a device which indicates whether gas flow is present in a vent stream.
Halogenated vent stream means any vent stream determined to have a total concentration (by volume) of compounds containing halogens of 20 ppmv (by compound) or greater.
Incinerator means any enclosed combustion device that is used for destroying organic compounds and does not extract energy in the form of steam or process heat.
Process heater means a device that transfers heat liberated by burning fuel to fluids contained in tubes, including all fluids except water that is heated to produce steam.
Process unit means equipment assembled and connected by pipes or ducts to produce, as intermediates or final products, one or more of the chemicals in § 60.667. A process unit can operate independently if supplied with sufficient fuel or raw materials and sufficient product storage facilities.
Product means any compound or chemical listed in § 60.667 that is produced for sale as a final product as that chemical, or for use in the production of other chemicals or compounds. By-products, co-products, and intermediates are considered to be products.
Recovery device means an individual unit of equipment, such as an absorber, carbon adsorber, or condenser, capable of and used for the purpose of recovering chemicals for use, reuse, or sale.
Recovery system means an individual recovery device or series of such devices applied to the same vent stream.
Total organic compounds (TOC) means those compounds measured according to the procedures in § 60.664(b)(4). For the purposes of measuring molar composition as required in § 60.664(d)(2)(i); hourly emissions rate as required in § 60.664(d)(5) and § 60.664(e); and TOC concentration as required in § 60.665(b)(4) and § 60.665(g)(4), those compounds which the Administrator has determined do not contribute appreciably to the formation of ozone are to be excluded. The compounds to be excluded are identified in Environmental Protection Agency's statements on ozone abatement policy for State Implementation Plans (SIP) revisions (42 FR 35314; 44 FR 32042; 45 FR 32424; 45 FR 48942).
TRE index value means a measure of the supplemental total resource requirement per unit reduction of TOC associated with an individual distillation vent stream, based on vent stream flow rate, emission rate of TOC net heating value, and corrosion properties (whether or not the vent stream is halogenated), as quantified by the equation given under § 60.664(e).
Vent stream means any gas stream discharged directly from a distillation facility to the atmosphere or indirectly to the atmosphere after diversion through other process equipment. The vent stream excludes relief valve discharges and equipment leaks including, but not limited to, pumps, compressors, and valves.
§ 60.662 - Standards.
Each owner or operator of any affected facility shall comply with paragraph (a), (b), or (c) of this section for each vent stream on and after the date on which the initial performance test required by §§ 60.8 and 60.664 is completed, but not later than 60 days after achieving the maximum production rate at which the affected facility will be operated, or 180 days after the initial start-up, whichever date comes first. Each owner or operator shall either:
(a) Reduce emissions of TOC (less methane and ethane) by 98 weight-percent, or to a TOC (less methane and ethane) concentration of 20 ppmv, on a dry basis corrected to 3 percent oxygen, whichever is less stringent. If a boiler or process heater is used to comply with this paragraph, then the vent stream shall be introduced into the flame zone of the boiler or process heater; or
(b) Combust the emissions in a flare that meets the requirements of § 60.18; or
(c) Maintain a TRE index value greater than 1.0 without use of VOC emission control devices.
§ 60.663 - Monitoring of emissions and operations.
(a) The owner or operator of an affected facility that uses an incinerator to seek to comply with the TOC emission limit specified under § 60.662(a) shall install, calibrate, maintain, and operate according to manufacturer's specifications the following equipment:
(1) A temperature monitoring device equipped with a continuous recorder and having an accuracy of ±1 percent of the temperature being monitored expressed in degrees Celsius or ±0.5 °C, whichever is greater.
(i) Where an incinerator other than a catalytic incinerator is used, a temperature monitoring device shall be installed in the firebox.
(ii) Where a catalytic incinerator is used, temperature monitoring devices shall be installed in the gas stream immediately before and after the catalyst bed.
(2) A flow indicator that provides a record of vent stream flow to the incinerator at least once every hour for each affected facility. The flow indicator shall be installed in the vent stream from each affected facility at a point closest to the inlet of each incinerator and before being joined with any other vent stream.
(b) The owner or operator of an affected facility that uses a flare to seek to comply with § 60.662(b) shall install, calibrate, maintain and operate according to manufacturer's specifications the following equipment:
(1) A heat sensing device, such as an ultra-violet beam sensor or thermocouple, at the pilot light to indicate the continuous presence of a flame.
(2) A flow indicator that provides a record of vent stream flow to the flare at least once every hour for each affected facility. The flow indicator shall be installed in the vent stream from each affected facility at a point closest to the flare and before being joined with any other vent stream.
(c) The owner or operator of an affected facility that uses a boiler or process heater to seek to comply with § 60.662(a) shall install, calibrate, maintain and operate according to the manufacturer's specifications the following equipment:
(1) A flow indicator that provides a record of vent stream flow to the boiler or process heater at least once every hour for each affected facility. The flow indicator shall be installed in the vent stream from each distillation unit within an affected facility at a point closest to the inlet of each boiler or process heater and before being joined with any other vent stream.
(2) A temperature monitoring device in the firebox equipped with a continuous recorder and having an accuracy of ±1 percent of the temperature being measured expressed in degrees Celsius or ±0.5 °C, whichever is greater, for boilers or process heaters of less than 44 MW (150 million Btu/hr) heat input design capacity.
(d) Monitor and record the periods of operation of the boiler or process heater if the design heat input capacity of the boiler or process heater is 44 MW (150 million Btu/hr) or greater. The records must be readily available for inspection.
(e) The owner or operator of an affected facility that seeks to comply with the TRE index value limit specified under § 60.662(c) shall install, calibrate, maintain, and operate according to manufacturer's specifications the following equipment, unless alternative monitoring procedures or requirements are approved for that facility by the Administrator:
(1) Where an absorber is the final recovery device in the recovery system:
(i) A scrubbing liquid temperature monitoring device having an accuracy of ±1 percent of the temperature being monitored expressed in degrees Celsius or ±0.5 °C, whichever is greater, and a specific gravity monitoring device having an accuracy of ±0.02 specific gravity units, each equipped with a continuous recorder, or
(ii) An organic monitoring device used to indicate the concentration level of organic compounds exiting the recovery device based on a detection principle such as infrared, photoionization, or thermal conductivity, each equipped with a continuous recorder.
(2) Where a condenser is the final recovery device in the recovery system:
(i) A condenser exit (product side) temperature monitoring device equipped with a continuous recorder and having an accuracy of ±1 percent of the temperature being monitored expressed in degrees Celsius or ±0.5 °C, whichever is greater, or
(ii) An organic monitoring device used to monitor organic compounds exiting the recovery device based on a detection principle such as infra-red, photoionization, or thermal conductivity, each equipped with a continuous recorder.
(3) Where a carbon adsorber is the final recovery device unit in the recovery system:
(i) An integrating steam flow monitoring device having an accuracy of ±10 percent, and a carbon bed temperature monitoring device having an accuracy of ±1 percent of the temperature being monitored expressed in degrees Celsius or ±0.5 °C, whichever is greater, both equipped with a continuous recorder, or
(ii) An organic monitoring device used to indicate the concentration level of organic compounds exiting the recovery device based on a detection principle such as infra-red, photoionization, or thermal conductivity, each equipped with a continuous recorder.
(f) An owner or operator of an affected facility seeking to demonstrate compliance with the standards specified under § 60.662 with control devices other than incinerator, boiler, process heater, or flare; or recovery device other than an absorber, condenser, or carbon adsorber shall provide to the Administrator information describing the operation of the control device or recovery device and the process parameter(s) which would indicate proper operation and maintenance of the device. The Administrator may request further information and will specify appropriate monitoring procedures or requirements.
§ 60.664 - Test methods and procedures.
(a) For the purpose of demonstrating compliance with § 60.662, all affected facilities shall be run at full operating conditions and flow rates during any performance test.
(b) The following methods in appendix A to this part, except as provided under § 60.8(b), shall be used as reference methods to determine compliance with the emission limit or percent reduction efficiency specified under § 60.662(a).
(1) Method 1 or 1A, as appropriate, for selection of the sampling sites. The control device inlet sampling site for determination of vent stream molar composition or TOC (less methane and ethane) reduction efficiency shall be prior to the inlet of the control device and after the recovery system.
(2) Method 2, 2A, 2C, or 2D, as appropriate, for determination of the gas volumetric flow rates.
(3) The emission rate correction factor, integrated sampling and analysis procedure of Method 3 shall be used to determine the oxygen concentration (%O
The TOC concentration corrected to 3 percent 0
where:
(4) Method 18 to determine the concentration of TOC in the control device outlet and the concentration of TOC in the inlet when the reduction efficiency of the control device is to be determined.
(i) The sampling time for each run shall be 1 hour in which either an integrated sample or four grab samples shall be taken. If grab sampling is used then the samples shall be taken at 15-minute intervals.
(ii) The emission reduction (R) of TOC (minus methane and ethane) shall be determined using the following equation:
where:
(iii) The mass rates of TOC (E
where:
(iv) The TOC concentration (C
where:
(c) When a boiler or process heater with a design heat input capacity of 44 MW (150 million Btu/hour) or greater is used to seek to comply with § 60.662(a), the requirement for an initial performance test is waived, in accordance with § 60.8(b). However, the Administrator reserves the option to require testing at such other times as may be required, as provided for in section 114 of the Act.
(d) When a flare is used to seek to comply with § 60.662(b), the flare shall comply with the requirements of § 60.18.
(e) The following test methods in appendix A to this part, except as provided under § 60.8(b), shall be used for determining the net heating value of the gas combusted to determine compliance under § 60.662(b) and for determining the process vent stream TRE index value to determine compliance under § 60.662(c).
(1)(i) Method 1 or 1A, as appropriate, for selection of the sampling site. The sampling site for the vent stream flow rate and molar composition determination prescribed in § 60.664(e)(2) and (3) shall be, except for the situations outlined in paragraph (e)(1)(ii) of this section, prior to the inlet of any control device, prior to any post-distillation dilution of the stream with air, and prior to any post-distillation introduction of halogenated compounds into the process vent stream. No transverse site selection method is needed for vents smaller than 10 centimeters (4 inches) in diameter.
(ii) If any gas stream other than the distillation vent stream from the affected facility is normally conducted through the final recovery device.
(A) The sampling site for vent stream flow rate and molar composition shall be prior to the final recovery device and prior to the point at which the nondistillation stream is introduced.
(B) The efficiency of the final recovery device is determined by measuring the TOC concentration using Method 18 at the inlet to the final recovery device after the introduction of any nondistillation vent stream and at the outlet of the final recovery device.
(C) This efficiency is applied to the TOC concentration measured prior to the final recovery device and prior to the introduction of the nondistillation stream to determine the concentration of TOC in the distillation vent stream from the final recovery device. This concentration of TOC is then used to perform the calculations outlined in § 60.664(e)(4) and (5).
(2) The molar composition of the process vent stream shall be determined as follows:
(i) Method 18 to measure the concentration of TOC including those containing halogens.
(ii) ASTM D1946-77 or 90 (Reapproved 1994) (incorporation by reference as specified in § 60.17 of this part) to measure the concentration of carbon monoxide and hydrogen.
(iii) Method 4 to measure the content of water vapor.
(3) The volumetric flow rate shall be determined using Method 2, 2A, 2C, or 2D, as appropriate.
(4) The net heating value of the vent stream shall be calculated using the following equation:
where:
The heats of combustion of vent stream components would be required to be determined using ASTM D2382-76 (incorporation by reference as specified in § 60.17 of this part) if published values are not available or cannot be calculated.
(5) The emission rate of TOC in the vent stream shall be calculated using the following equation:
where:
(6) The total process vent stream concentration (by volume) of compounds containing halogens (ppmv, by compound) shall be summed from the individual concentrations of compounds containing halogens which were measured by Method 18.
(f) For purposes of complying with § 60.662(c) the owner or operator of a facility affected by this subpart shall calculate the TRE index value of the vent stream using the equation for incineration in paragraph (e)(1) of this section for halogenated vent streams. The owner or operator of an affected facility with a nonhalogenated vent stream shall determine the TRE index value by calculating values using both the incinerator equation in (e)(1) and the flare equation in (e)(2) of this section and selecting the lower of the two values.
(1) The equation for calculating the TRE index value of a vent stream controlled by an incinerator is as follows:
(i) Where for a vent stream flow rate that is greater than or equal to 14.2 scm/min (501 scf/min) at a standard temperature of 20 °C (68 °F):
a, b, c, d, e, and f are coefficients.
The set of coefficients that apply to a vent stream can be obtained from table 1.
(ii) Where for a vent stream flow rate that is less than 14.2 scm/min (501 scf/min) at a standard temperature of 20 °C (68 °F):
a, b, c, d, e, and f are coefficients
The set of coefficients that apply to a vent stream can be obtained from table 1.
(2) The equation for calculating the TRE index value of a vent stream controlled by a flare is as follows:
where:
a, b, c, d, and e are coefficients.
The set of coefficients that apply to a vent stream shall be obtained from table 2.
Table 2—Distillation NSPS TRE Coefficients for Vent Streams Controlled By a Flare
| a | b | c | d | e | H | 2.25 | 0.288 | −0.193 | −0.0051 | 2.08 | (H | (0.140) | (0.0367) | (−0.000448) | (−0.0051) | (4.59) | H | 0.309 | 0.0619 | −0.0043 | −0.0034 | 2.08 | (H | (0.0193) | (0.00788) | (−0.0000010) | (−0.0034) | (4.59) |
|---|
(g) Each owner or operator of an affected facility seeking to comply with § 60.660(c)(4) or § 60.662(c) shall recalculate the TRE index value for that affected facility whenever process changes are made. Examples of process changes include changes in production capacity, feedstock type, or catalyst type, or whenever there is replacement, removal, or addition of recovery equipment. The TRE index value shall be recalculated based on test data, or on best engineering estimates of the effects of the change to the recovery system.
(1) Where the recalculated TRE index value is less than or equal to 1.0, the owner or operator shall notify the Administrator within 1 week of the recalculation and shall conduct a performance test according to the methods and procedures required by § 60.664 in order to determine compliance with § 60.662(a). Performance tests must be conducted as soon as possible after the process change but no later than 180 days from the time of the process change.
(2) Where the initial TRE index value is greater than 8.0 and the recalculated TRE index value is less than or equal to 8.0 but greater than 1.0, the owner or operator shall conduct a performance test in accordance with §§ 60.8 and 60.664 and shall comply with §§ 60.663, 60.664 and 60.665. Performance tests must be conducted as soon as possible after the process change but no later than 180 days from the time of the process change.
(h) Any owner or operator subject to the provisions of this subpart seeking to demonstrate compliance with § 60.660(c)(6) shall use Method 2, 2A, 2C, or 2D as appropriate, for determination of volumetric flow rate.
§ 60.665 - Reporting and recordkeeping requirements.
(a) Each owner or operator subject to § 60.662 shall notify the Administrator of the specific provisions of § 60.662 (§ 60.662 (a), (b), or (c)) with which the owner or operator has elected to comply. Notification shall be submitted with the notification of initial start-up required by § 60.7(a)(3). If an owner or operator elects at a later date to use an alternative provision of § 60.662 with which he or she will comply, then the Administrator shall be notified by the owner or operator 90 days before implementing a change and, upon implementing the change, a performance test shall be performed as specified by § 60.664 within 180 days.
(b) Each owner or operator subject to the provisions of this subpart shall keep an up-to-date, readily accessible record of the following data measured during each performance test, and also include the following data in the report of the initial performance test required under § 60.8. Where a boiler or process heater with a design heat input capacity of 44 MW (150 million Btu/hour) or greater is used to comply with § 60.662(a), a report containing performance test data need not be submitted, but a report containing the information in § 60.665(b)(2)(i) is required. The same data specified in this section shall be submitted in the reports of all subsequently required performance tests where either the emission control efficiency of a control device, outlet concentration of TOC, or the TRE index value of a vent stream from a recovery system is determined.
(1) Where an owner or operator subject to the provisions of this subpart seeks to demonstrate compliance with § 60.662(a) through use of either a thermal or catalytic incinerator:
(i) The average firebox temperature of the incinerator (or the average temperature upstream and downstream of the catalyst bed for a catalytic incinerator), measured at least every 15 minutes and averaged over the same time period of the performance testing, and
(ii) The percent reduction of TOC determined as specified in § 60.664(b) achieved by the incinerator, or the concentration of TOC (ppmv, by compound) determined as specified in § 60.664(b) at the outlet of the control device on a dry basis corrected to 3 percent oxygen.
(2) Where an owner or operator subject to the provisions of this subpart seeks to demonstrate compliance with § 60.662(a) through use of a boiler or process heater:
(i) A description of the location at which the vent stream is introduced into the boiler or process heater, and
(ii) The average combustion temperature of the boiler or process heater with a design heat input capacity of less than 44 MW (150 million Btu/hr) measured at least every 15 minutes and averaged over the same time period of the performance testing.
(3) Where an owner or operator subject to the provisions of this subpart seeks to demonstrate compliance with § 60.662(b) through use of a smokeless flare, flare design (i.e., steam-assisted, air-assisted or nonassisted), all visible emission readings, heat content determinations, flow rate measurements, and exit velocity determinations made during the performance test, continuous records of the flare pilot flame monitoring, and records of all periods of operations during which the pilot flame is absent.
(4) Where an owner or operator subject to the provisions of this subpart seeks to demonstrate compliance with § 60.662(c):
(i) Where an absorber is the final recovery device in the recovery system, the exit specific gravity (or alternative parameter which is a measure of the degree of absorbing liquid saturation, if approved by the Administrator), and average exit temperature, of the absorbing liquid measured at least every 15 minutes and averaged over the same time period of the performance testing (both measured while the vent stream is normally routed and constituted), or
(ii) Where a condenser is the final recovery device in the recovery system, the average exit (product side) temperature measured at least every 15 minutes and averaged over the same time period of the performance testing while the vent stream is routed and constituted normally, or
(iii) Where a carbon adsorber is the final recovery device in the recovery system, the total steam mass flow measured at least every 15 minutes and averaged over the same time period of the performance test (full carbon bed cycle), temperature of the carbon bed after regeneration (and within 15 minutes of completion of any cooling cycle(s)), and duration of the carbon bed steaming cycle (all measured while the vent stream is routed and constituted normally), or
(iv) As an alternative to § 60.665(b)(4) ((i), (ii) or (iii), the concentration level or reading indicated by the organics monitoring device at the outlet of the absorber, condenser, or carbon adsorber, measured at least every 15 minutes and averaged over the same time period of the performance testing while the vent stream is normally routed and constituted.
(v) All measurements and calculations performed to determine the TRE index value of the vent stream.
(c) Each owner or operator subject to the provisions of this subpart shall keep up-to-date, readily accessible continuous records of the equipment operating parameters specified to be monitored under § 60.663 (a) and (c) as well as up-to-date, readily accessible records of periods of operation during which the parameter boundaries established during the most recent performance test are exceeded. The Administrator may at any time require a report of these data. Where a combustion device is used to comply with § 60.662(a), periods of operation during which the parameter boundaries established during the most recent performance tests are exceeded are defined as follows:
(1) For thermal incinerators, all 3-hour periods of operation during which the average combustion temperature was more than 28 °C (50 °F) below the average combustion temperature during the most recent performance test at which compliance with § 60.662(a) was determined.
(2) For catalytic incinerators, all 3-hour periods of operation during which the average temperature of the vent stream immediately before the catalyst bed is more than 28 °C (50 °F) below the average temperature of the vent stream during the most recent performance test at which compliance with § 60.662(a) was determined. The owner or operator also shall record all 3-hour periods of operation during which the average temperature difference across the catalyst bed is less than 80 percent of the average temperature difference of the device during the most recent performance test at which compliance with § 60.662(a) was determined.
(3) All 3-hour periods of operation during which the average combustion temperature was more than 28 °C (50 °F) below the average combustion temperature during the most recent performance test at which compliance with § 60.662(a) was determined for boilers or process heaters with a design heat input capacity of less than 44 MW (150 million Btu/hr).
(4) For boilers or process heaters, whenever there is a change in the location at which the vent stream is introduced into the flame zone as required under § 60.662(a).
(d) Each owner or operator subject to the provisions of this subpart shall keep up to date, readily accessible continuous records of the flow indication specified under § 60.663(a)(2), § 60.663(b)(2) and § 60.663(c)(1), as well as up-to-date, readily accessible records of all periods when the vent stream is diverted from the control device or has no flow rate.
(e) Each owner or operator subject to the provisions of this subpart who uses a boiler or process heater with a design heat input capacity of 44 MW (150 million Btu/hour) or greater to comply with § 60.662(a) shall keep an up-to-date, readily accessible record of all periods of operation of the boiler or process heater. (Examples of such records could include records of steam use, fuel use, or monitoring data collected pursuant to other State or Federal regulatory requirements.)
(f) Each owner or operator subject to the provisions of this subpart shall keep up-to-date, readily accessible continuous records of the flare pilot flame monitoring specified under § 60.663(b), as well as up-to-date, readily accessible records of all periods of operations in which the pilot flame is absent.
(g) Each owner or operator subject to the provisions of this subpart shall keep up-to-date, readily accessible continuous records of the equipment operating parameters specified to be monitored under § 60.663(e), as well as up-to-date, readily accessible records of periods of operation during which the parameter boundaries established during the most recent performance test are exceeded. The Administrator may at any time require a report of these data. Where an owner or operator seeks to comply with § 60.662(c), periods of operation during which the parameter boundaries established during the most recent performance tests are exceeded are defined as follows:
(1) Where an absorber is the final recovery device in a recovery system, and where an organic compound monitoring device is not used:
(i) All 3-hour periods of operation during which the average absorbing liquid temperature was more than 11 °C (20 °F) above the average absorbing liquid temperature during the most recent performance test, or
(ii) All 3-hour periods of operation during which the average absorbing liquid specific gravity was more than 0.1 unit above, or more than 0.1 unit below, the average absorbing liquid specific gravity during the most recent performance test (unless monitoring of an alternative parameter, which is a measure of the degree of absorbing liquid saturation, is approved by the Administrator, in which case he will define appropriate parameter boundaries and periods of operation during which they are exceeded).
(2) Where a condenser is the final recovery device in a system, and where an organic compound monitoring device is not used, all 3-hour periods of operation during which the average exit (product side) condenser operating temperature was more than 6 °C (1 1 °F) above the average exit (product side) operating temperature during the most recent performance test.
(3) Where a carbon adsorber is the final recovery device in a system, and where an organic compound monitoring device is not used:
(i) All carbon bed regeneration cycles during which the total mass steam flow was more than 10 percent below the total mass steam flow during the most recent performance test, or
(ii) All carbon bed regeneration cycles during which the temperature of the carbon bed after regeneration (and after completion of any cooling cycle(s)) was more than 10 percent greater than the carbon bed temperature (in degrees Celsius) during the most recent performance test.
(4) Where an absorber, condenser, or carbon adsorber is the final recovery device in the recovery system and where an organic compound monitoring device is used, all 3-hour periods of operation during which the average organic compound concentration level or reading of organic compounds in the exhaust gases is more than 20 percent greater than the exhaust gas organic compound concentration level or reading measured by the monitoring device during the most recent performance test.
(h) Each owner or operator of an affected facility subject to the provisions of this subpart and seeking to demonstrate compliance with § 60.662(c) shall keep up-to-date, readily accessible records of:
(1) Any changes in production capacity, feedstock type, or catalyst type, or of any replacement, removal or addition of recovery equipment or a distillation unit;
(2) Any recalculation of the TRE index value performed pursuant to § 60.664(g); and
(3) The results of any performance test performed pursuant to the methods and procedures required by § 60.664(e).
(i) Each owner or operator of an affected facility that seeks to comply with the requirements of this subpart by complying with the flow rate cutoff in § 60.660(c)(6) shall keep up-to-date, readily accessible records to indicate that the vent stream flow rate is less than 0.008 scm/min (0.3 scf/min) and of any change in equipment or process operation that increases the operating vent stream flow rate, including a measurement of the new vent stream flow rate.
(j) Each owner or operator of an affected facility that seeks to comply with the requirements of this subpart by complying with the design production capacity provision in § 60.660(c)(5) shall keep up-to-date, readily accessible records of any change in equipment or process operation that increases the design production capacity of the process unit in which the affected facility is located.
(k) Each owner and operator subject to the provisions of this subpart is exempt from the quarterly reporting requirements contained in § 60.7(c) of the General Provisions.
(l) Each owner or operator that seeks to comply with the requirements of this subpart by complying with the requirements of § 60.660 (c)(4), (c)(5), or (c)(6) or § 60.662 shall submit to the Administrator semiannual reports of the following recorded information. The initial report shall be submitted within 6 months after the initial start-up date.
(1) Exceedances of monitored parameters recorded under § 60.665 (c) and (g).
(2) All periods recorded under § 60.665(d) when the vent stream is diverted from the control device or has no flow rate.
(3) All periods recorded under § 60.665(e) when the boiler or process heater was not operating.
(4) All periods recorded under § 60.665(f) in which the pilot flame of the flare was absent.
(5) Any change in equipment or process operation that increases the operating vent stream flow rate above the low flow exemption level in § 60.660(c)(6), including a measurement of the new vent stream flow rate, as recorded under § 60.665(i). These must be reported as soon as possible after the change and no later than 180 days after the change. These reports may be submitted either in conjunction with semiannual reports or as a single separate report. A performance test must be completed with the same time period to verify the recalculated flow value and to obtain the vent stream characteristics of heating value and E
(6) Any change in equipment or process operation, as recorded under paragraph (j) of this section, that increases the design production capacity above the low capacity exemption level in § 60.660(c)(5) and the new capacity resulting from the change for the distillation process unit containing the affected facility. These must be reported as soon as possible after the change and no later than 180 days after the change. These reports may be submitted either in conjunction with semiannual reports or as a single separate report. A performance test must be completed within the same time period to obtain the vent stream flow rate, heating value, and E
(7) Any recalculation of the TRE index value, as recorded under § 60.665(h).
(m) The requirements of § 60.665(l) remain in force until and unless EPA, in delegating enforcement authority to a State under section 111(c) of the Act, approves reporting requirements or an alternative means of compliance surveillance adopted by such State. In that event, affected sources within the State will be relieved of the obligation to comply with § 60.665(l), provided that they comply with the requirements established by the State.
(n) Each owner or operator that seeks to demonstrate compliance with § 60.660(c)(5) must submit to the Administrator an initial report detailing the design production capacity of the process unit.
(o) Each owner or operator that seeks to demonstrate compliance with § 60.660(c)(6) must submit to the Administrator an initial report including a flow rate measurement using the test methods specified in § 60.664.
(p) The Administrator will specify appropriate reporting and recordkeeping requirements where the owner or operator of an affected facility complies with the standards specified under § 60.662 other than as provided under § 60.663(a), (b), (c) and (d).
§ 60.666 - Reconstruction.
For purposes of this subpart “fixed capital cost of the new components,” as used in § 60.15, includes the fixed capital cost of all depreciable components which are or will be replaced pursuant to all continuous programs of component replacement which are commenced within any 2-year period following December 30, 1983. For purposes of this paragraph, “commenced” means that an owner or operator has undertaken a continuous program of component replacement or that an owner or operator has entered into a contractual obligation to undertake and complete, within a reasonable time, a continuous program of component replacement.
§ 60.667 - Chemicals affected by subpart NNN.
| Chemical name | CAS No.* | Acetaldehyde | 75-07-0 | Acetaldol | 107-89-1 | Acetic acid | 64-19-7 | Acetic anhydride | 108-24-7 | Acetone | 67-64-1 | Acetone cyanohydrin | 75-86-5 | Acetylene | 74-86-2 | Acrylic acid | 79-10-7 | Acrylonitrile | 107-13-1 | Adipic acid | 124-04-9 | Adiponitrile | 111-69-3 | Alcohols, C-11 or lower, mixtures | Alcohols, C-12 or higher, mixtures | Allyl chloride | 107-05-1 | Amylene | 513-35-9 | Amylenes, mixed | Aniline | 62-53-3 | Benzene | 71-43-2 | Benzenesulfonic acid | 98-11-3 | Benzenesulfonic acid C | 68081-81-2 | Benzoic acid, tech | 65-85-0 | Benzyl chloride | 100-44-7 | Biphenyl | 92-52-4 | Bisphenol A | 80-05-7 | Brometone | 76-08-4 | 1,3-Butadiene | 106-99-0 | Butadiene and butene fractions | n-Butane | 106-97-8 | 1,4-Butanediol | 110-63-4 | Butanes, mixed | 1-Butene | 106-98-9 | 2-Butene | 25167-67-3 | Butenes, mixed | n-Butyl acetate | 123-86-4 | Butyl acrylate | 141-32-2 | n-Butyl alcohol | 71-36-3 | sec-Butyl alcohol | 78-92-2 | tert-Butyl alcohol | 75-65-0 | Butylbenzyl phthalate | 85-68-7 | Butylene glycol | 107-88-0 | tert-Butyl hydroperoxide | 75-91-2 | 2-Butyne-1,4-diol | 110-65-6 | Butyraldehyde | 123-72-8 | Butyric anhydride | 106-31-0 | Caprolactam | 105-60-2 | Carbon disulfide | 75-15-0 | Carbon tetrabromide | 558-13-4 | Carbon tetrachloride | 56-23-5 | Chlorobenzene | 108-90-7 | 2-Chloro-4-(ethylamino)-6-(isopropylamino)-s-triazine | 1912-24-9 | Chloroform | 67-66-3 | p-Chloronitrobenzene | 100-00-5 | Chloroprene | 126-99-8 | Citric acid | 77-92-9 | Crotonaldehyde | 4170-30-0 | Crotonic acid | 3724-65-0 | Cumene | 98-82-8 | Cumene hydroperoxide | 80-15-9 | Cyanuric chloride | 108-77-0 | Cyclohexane | 110-82-7 | Cyclohexane, oxidized | 68512-15-2 | Cyclohexanol | 108-93-0 | Cyclohexanone | 108-94-1 | Cyclohexanone oxime | 100-64-1 | Cyclohexene | 110-83-8 | 1,3-Cyclopentadiene | 542-92-7 | Cyclopropane | 75-19-4 | Diacetone alcohol | 123-42-2 | Dibutanized aromatic concentrate | 1,4-Dichlorobutene | 110-57-6 | 3,4-Dichloro-1-butene | 64037-54-3 | Dichlorodifluoromethane | 75-71-8 | Dichlorodimethylsilane | 75-78-5 | Dichlorofluoromethane | 75-43-4 | -Dichlorohydrin | 96-23-1 | Diethanolamine | 111-42-2 | Diethylbenzene | 25340-17-4 | Diethylene glycol | 111-46-6 | Di-n-heptyl-n-nonyl undecyl phthalate | 85-68-7 | Di-isodecyl phthalate | 26761-40-0 | Diisononyl phthalate | 28553-12-0 | Dimethylamine | 124-40-3 | Dimethyl terephthalate | 120-61-6 | 2,4-Dinitrotoluene | 121-14-2 | 2,4-(and 2,6)-dinitrotoluene | 121-14-2 | 606-20-2 | Dioctyl phthalate | 117-81-7 | Dodecene | 25378-22-7 | Dodecylbenzene, non linear | Dodecylbenzenesulfonic acid | 27176-87-0 | Dodecylbenzenesulfonic acid, sodium salt | 25155-30-0 | Epichlorohydrin | 106-89-8 | Ethanol | 64-17-5 | Ethanolamine | 141-43-5 | Ethyl acetate | 141-78-6 | Ethyl acrylate | 140-88-5 | Ethylbenzene | 100-41-4 | Ethyl chloride | 75-00-3 | Ethyl cyanide | 107-12-0 | Ethylene | 74-85-1 | Ethylene dibromide | 106-93-4 | Ethylene dichloride | 107-06-2 | Ethylene glycol | 107-21-1 | Ethylene glycol monobutyl | 111-76-2 | Ethylene glycol monoethyl ether | 110-80-5 | Ethylene glycol monoethyl ether acetate | 111-15-9 | Ethylene glycol monomethyl ether | 109-86-4 | Ethylene oxide | 75-21-8 | 2-Ethylhexanal | 26266-68-2 | 2-Ethylhexyl alcohol | 104-76-7 | (2-Ethylhexyl) amine | 104-75-6 | Ethylmethylbenzene | 25550-14-5 | 6-Ethyl-1,2,3,4-tetrahydro 9,10-anthracenedione | 15547-17-8 | Formaldehyde | 50-00-0 | Glycerol | 56-81-5 | n-Heptane | 142-82-5 | Heptenes (mixed) | Hexadecyl chloride | Hexamethylene diamine | 124-09-4 | Hexamethylene diamine adipate | 3323-53-3 | Hexamethylenetetramine | 100-97-0 | Hexane | 110-54-3 | 2-Hexenedinitrile | 13042-02-9 | 3-Hexenedinitrile | 1119-85-3 | Hydrogen cyanide | 74-90-8 | Isobutane | 75-28-5 | Isobutanol | 78-83-1 | Isobutylene | 115-11-7 | Isobutyraldehyde | 78-84-2 | Isodecyl alcohol | 25339-17-7 | Isooctyl alcohol | 26952-21-6 | Isopentane | 78-78-4 | Isophthalic acid | 121-91-5 | Isoprene | 78-79-5 | Isopropanol | 67-63-0 | Ketene | 463-51-4 | Linear alcohols, ethoxylated, mixed | Linear alcohols, ethoxylated, and sulfated, sodium salt, mixed | Linear alcohols, sulfated, sodium salt, mixed | Linear alkylbenzene | 123-01-3 | Magnesium acetate | 142-72-3 | Maleic anhydride | 108-31-6 | Melamine | 108-78-1 | Mesityl oxide | 141-79-7 | Methacrylonitrile | 126-98-7 | Methanol | 67-56-1 | Methylamine | 74-89-5 | ar-Methylbenzenediamine | 25376-45-8 | Methyl chloride | 74-87-3 | Methylene chloride | 75-09-2 | Methyl ethyl ketone | 78-93-3 | Methyl iodide | 74-88-4 | Methyl isobutyl ketone | 108-10-1 | Methyl methacrylate | 80-62-6 | 2-Methylpentane | 107-83-5 | 1-Methyl-2-pyrrolidone | 872-50-4 | Methyl tert-butyl ether | Naphthalene | 91-20-3 | Nitrobenzene | 98-95-3 | 1-Nonene | 27215-95-8 | Nonyl alcohol | 143-08-8 | Nonylphenol | 25154-52-3 | Nonylphenol, ethoxylated | 9016-45-9 | Octene | 25377-83-7 | Oil-soluble petroleum sulfonate, calcium salt | Oil-soluble petroleum sulfonate, sodium salt | Pentaerythritol | 115-77-5 | n-Pentane | 109-66-0 | 3-Pentenenitrile | 4635-87-4 | Pentenes, mixed | 109-67-1 | Perchloroethylene | 127-18-4 | Phenol | 108-95-2 | 1-Phenylethyl hydroperoxide | 3071-32-7 | Phenylpropane | 103-65-1 | Phosgene | 75-44-5 | Phthalic anhydride | 85-44-9 | Propane | 74-98-6 | Propionaldehyde | 123-38-6 | Propionic acid | 79-09-4 | Propyl alcohol | 71-23-8 | Propylene | 115-07-1 | Propylene chlorohydrin | 78-89-7 | Propylene glycol | 57-55-6 | Propylene oxide | 75-56-9 | Sodium cyanide | 143-33-9 | Sorbitol | 50-70-4 | Styrene | 100-42-5 | Terephthalic acid | 100-21-0 | 1,1,2,2-Tetrachloroethane | 79-34-5 | Tetraethyl lead | 78-00-2 | Tetrahydrofuran | 109-99-9 | Tetra (methyl-ethyl) lead | Tetramethyl lead | 75-74-1 | Toluene | 108-88-3 | Toluene-2,4-diamine | 95-80-7 | Toluene-2,4-(and, 2,6)-diisocyanate (80/20 mixture) | 26471-62-5 | Tribromomethane | 75-25-2 | 1,1,1-Trichloroethane | 71-55-6 | 1,1,2-Trichloroethane | 79-00-5 | Trichloroethylene | 79-01-6 | Trichlorofluoromethane | 75-69-4 | 1,1,2-Trichloro-1,2,2-trifluoroethane | 76-13-1 | Triethanolamine | 102-71-6 | Triethylene glycol | 112-27-6 | Vinyl acetate | 108-05-4 | Vinyl chloride | 75-01-4 | Vinylidene chloride | 75-35-4 | m-Xylene | 108-38-3 | o-Xylene | 95-47-6 | p-Xylene | 106-42-3 | Xylenes (mixed) | 1330-20-7 | m-Xylenol | 576-26-1 |
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* CAS numbers refer to the Chemical Abstracts Registry numbers assigned to specific chemicals, isomers, or mixtures of chemicals. Some isomers or mixtures that are covered by the standards do not have CAS numbers assigned to them. The standards apply to all of the chemicals listed, whether CAS numbers have been assigned or not.
§ 60.668 - Delegation of authority.
(a) In delegating implementation and enforcement authority to a State under § 111(c) of the Act, the authorities contained in paragraph (b) of this section shall be retained by the Administrator and not transferred to a State.
(b) Authorities which will not be delegated to States: § 60.663(e).