Appendix D to Part 122—NPDES Permit Application Testing Requirements (§ 122.21)

Appendix D - Appendix D to Part 122—NPDES Permit Application Testing Requirements (§ 122.21)

Table I—Testing Requirements for Organic Toxic Pollutants by Industrial Category for Existing Dischargers

Industrial category	GC/MS Fraction 1				Volatile	Acid	Base/neutral	Pesticide	Adhesives and Sealants	2	2	2		Aluminum Forming	2	2	2		Auto and Other Laundries	2	2	2	2	Battery Manufacturing	2		2		Coal Mining	2	2	2	2	Coil Coating	2	2	2		Copper Forming	2	2	2		Electric and Electronic Components	2	2	2	2	Electroplating	2	2	2		Explosives Manufacturing		2	2		Foundries	2	2	2		Gum and Wood Chemicals	2	2	2	2	Inorganic Chemicals Manufacturing	2	2	2		Iron and Steel Manufacturing	2	2	2		Leather Tanning and Finishing	2	2	2	2	Mechanical Products Manufacturing	2	2	2		Nonferrous Metals Manufacturing	2	2	2	2	Ore Mining	2	2	2	2	Organic Chemicals Manufacturing	2	2	2	2	Paint and Ink Formulation	2	2	2	2	Pesticides	2	2	2	2	Petroleum Refining	2	2	2	2	Pharmaceutical Preparations	2	2	2		Photographic Equipment and Supplies	2	2	2	2	Plastic and Synthetic Materials Manufacturing	2	2	2	2	Plastic Processing	2				Porcelain Enameling	2		2	2	Printing and Publishing	2	2	2	2	Pulp and Paper Mills	2	2	2	2	Rubber Processing	2	2	2		Soap and Detergent Manufacturing	2	2	2		Steam Electric Power Plants	2	2	2		Textile Mills	2	2	2	2	Timber Products Processing	2	2	2	2

1 The toxic pollutants in each fraction are listed in Table II.

2 Testing required.

Table II—Organic Toxic Pollutants in Each of Four Fractions in Analysis by Gas Chromatography/Mass Spectroscopy (GS/MS) Volatiles 1V acrolein 2V acrylonitrile 3V benzene 5V bromoform 6V carbon tetrachloride 7V chlorobenzene 8V chlorodibromomethane 9V chloroethane 10V 2-chloroethylvinyl ether 11V chloroform 12V dichlorobromomethane 14V 1,1-dichloroethane 15V 1,2-dichloroethane 16V 1,1-dichloroethylene 17V 1,2-dichloropropane 18V 1,3-dichloropropylene 19V ethylbenzene 20V methyl bromide 21V methyl chloride 22V methylene chloride 23V 1,1,2,2-tetrachloroethane 24V tetrachloroethylene 25V toluene 26V 1,2-trans-dichloroethylene 27V 1,1,1-trichloroethane 28V 1,1,2-trichloroethane 29V trichloroethylene 31V vinyl chloride Acid Compounds 1A 2-chlorophenol 2A 2,4-dichlorophenol 3A 2,4-dimethylphenol 4A 4,6-dinitro-o-cresol 5A 2,4-dinitrophenol 6A 2-nitrophenol 7A 4-nitrophenol 8A p-chloro-m-cresol 9A pentachlorophenol 10A phenol 11A 2,4,6-trichlorophenol Base/Neutral 1B acenaphthene 2B acenaphthylene 3B anthracene 4B benzidine 5B benzo(a)anthracene 6B benzo(a)pyrene 7B 3,4-benzofluoranthene 8B benzo(ghi)perylene 9B benzo(k)fluoranthene 10B bis(2-chloroethoxy)methane 11B bis(2-chloroethyl)ether 12B bis(2-chloroisopropyl)ether 13B bis (2-ethylhexyl)phthalate 14B 4-bromophenyl phenyl ether 15B butylbenzyl phthalate 16B 2-chloronaphthalene 17B 4-chlorophenyl phenyl ether 18B chrysene 19B dibenzo(a,h)anthracene 20B 1,2-dichlorobenzene 21B 1,3-dichlorobenzene 22B 1,4-dichlorobenzene 23B 3,3′-dichlorobenzidine 24B diethyl phthalate 25B dimethyl phthalate 26B di-n-butyl phthalate 27B 2,4-dinitrotoluene 28B 2,6-dinitrotoluene 29B di-n-octyl phthalate 30B 1,2-diphenylhydrazine (as azobenzene) 31B fluroranthene 32B fluorene 33B hexachlorobenzene 34B hexachlorobutadiene 35B hexachlorocyclopentadiene 36B hexachloroethane 37B indeno(1,2,3-cd)pyrene 38B isophorone 39B napthalene 40B nitrobenzene 41B N-nitrosodimethylamine 42B N-nitrosodi-n-propylamine 43B N-nitrosodiphenylamine 44B phenanthrene 45B pyrene 46B 1,2,4-trichlorobenzene Pesticides 1P aldrin 2P alpha-BHC 3P beta-BHC 4P gamma-BHC 5P delta-BHC 6P chlordane 7P 4,4′-DDT 8P 4,4′-DDE 9P 4,4′-DDD 10P dieldrin 11P alpha-endosulfan 12P beta-endosulfan 13P endosulfan sulfate 14P endrin 15P endrin aldehyde 16P heptachlor 17P heptachlor epoxide 18P PCB-1242 19P PCB-1254 20P PCB-1221 21P PCB-1232 22P PCB-1248 23P PCB-1260 24P PCB-1016 25P toxaphene Table III—Other Toxic Pollutants (Metals and Cyanide) and Total Phenols Antimony, Total Arsenic, Total Beryllium, Total Cadmium, Total Chromium, Total Copper, Total Lead, Total Mercury, Total Nickel, Total Selenium, Total Silver, Total Thallium, Total Zinc, Total Cyanide, Total Phenols, Total Table IV—Conventional and Nonconventional Pollutants Required To Be Tested by Existing Dischargers if Expected to be Present Bromide Chlorine, Total Residual Color Fecal Coliform Fluoride Nitrate-Nitrite Nitrogen, Total Organic Oil and Grease Phosphorus, Total Radioactivity Sulfate Sulfide Sulfite Surfactants Aluminum, Total Barium, Total Boron, Total Cobalt, Total Iron, Total Magnesium, Total Molybdenum, Total Manganese, Total Tin, Total Titanium, Total Table V—Toxic Pollutants and Hazardous Substances Required To Be Identified by Existing Dischargers if Expected To Be Present Toxic Pollutants Asbestos Hazardous Substances Acetaldehyde Allyl alcohol Allyl chloride Amyl acetate Aniline Benzonitrile Benzyl chloride Butyl acetate Butylamine Captan Carbaryl Carbofuran Carbon disulfide Chlorpyrifos Coumaphos Cresol Crotonaldehyde Cyclohexane 2,4-D (2,4-Dichlorophenoxy acetic acid) Diazinon Dicamba Dichlobenil Dichlone 2,2-Dichloropropionic acid Dichlorvos Diethyl amine Dimethyl amine Dintrobenzene Diquat Disulfoton Diuron Epichlorohydrin Ethion Ethylene diamine Ethylene dibromide Formaldehyde Furfural Guthion Isoprene Isopropanolamine Dodecylbenzenesulfonate Kelthane Kepone Malathion Mercaptodimethur Methoxychlor Methyl mercaptan Methyl methacrylate Methyl parathion Mevinphos Mexacarbate Monoethyl amine Monomethyl amine Naled Napthenic acid Nitrotoluene Parathion Phenolsulfanate Phosgene Propargite Propylene oxide Pyrethrins Quinoline Resorcinol Strontium Strychnine Styrene 2,4,5-T (2,4,5-Trichlorophenoxy acetic acid) TDE (Tetrachlorodiphenylethane) 2,4,5-TP [2-(2,4,5-Trichlorophenoxy) propanoic acid] Trichlorofan Triethanolamine dodecylbenzenesulfonate Triethylamine Trimethylamine Uranium Vanadium Vinyl acetate Xylene Xylenol Zirconium

[Note 1: The Environmental Protection Agency has suspended the requirements of § 122.21(g)(7)(ii)(A) and Table I of Appendix D as they apply to certain industrial categories. The suspensions are as follows:

a. At 46 FR 2046, Jan. 8, 1981, the Environmental Protection Agency suspended until further notice § 122.21(g)(7)(ii)(A) as it applies to coal mines.

b. At 46 FR 22585, Apr. 20, 1981, the Environmental Protection Agency suspended until further notice § 122.21(g)(7)(ii)(A) and the corresponding portions of Item V-C of the NPDES application Form 2c as they apply to:

1. Testing and reporting for all four organic fractions in the Greige Mills Subcategory of the Textile Mills industry (Subpart C—Low water use processing of 40 CFR part 410), and testing and reporting for the pesticide fraction in all other subcategories of this industrial category.

2. Testing and reporting for the volatile, base/neutral and pesticide fractions in the Base and Precious Metals Subcategory of the Ore Mining and Dressing industry (subpart B of 40 CFR part 440), and testing and reporting for all four fractions in all other subcategories of this industrial category.

3. Testing and reporting for all four GC/MS fractions in the Porcelain Enameling industry.

c. At 46 FR 35090, July 1, 1981, the Environmental Protection Agency suspended until further notice § 122.21(g)(7)(ii)(A) and the corresponding portions of Item V-C of the NPDES application Form 2c as they apply to:

1. Testing and reporting for the pesticide fraction in the Tall Oil Rosin Subcategory (subpart D) and Rosin-Based Derivatives Subcategory (subpart F) of the Gum and Wood Chemicals industry (40 CFR part 454), and testing and reporting for the pesticide and base/netural fractions in all other subcategories of this industrial category.

2. Testing and reporting for the pesticide fraction in the Leather Tanning and Finishing, Paint and Ink Formulation, and Photographic Supplies industrial categories.

3. Testing and reporting for the acid, base/neutral and pesticide fractions in the Petroleum Refining industrial category.

4. Testing and reporting for the pesticide fraction in the Papergrade Sulfite subcategories (subparts J and U) of the Pulp and Paper industry (40 CFR part 430); testing and reporting for the base/neutral and pesticide fractions in the following subcategories: Deink (subpart Q), Dissolving Kraft (subpart F), and Paperboard from Waste Paper (subpart E); testing and reporting for the volatile, base/neutral and pesticide fractions in the following subcategories: BCT Bleached Kraft (subpart H), Semi-Chemical (subparts B and C), and Nonintegrated-Fine Papers (subpart R); and testing and reporting for the acid, base/neutral, and pesticide fractions in the following subcategories: Fine Bleached Kraft (subpart I), Dissolving Sulfite Pulp (subpart K), Groundwood-Fine Papers (subpart O), Market Bleached Kraft (subpart G), Tissue from Wastepaper (subpart T), and Nonintegrated-Tissue Papers (subpart S).

5. Testing and reporting for the base/neutral fraction in the Once-Through Cooling Water, Fly Ash and Bottom Ash Transport Water process wastestreams of the Steam Electric Power Plant industrial category.

This revision continues these suspensions.]*

* Editorial Note: The words “This revision” refer to the document published at 48 FR 14153, Apr. 1, 1983.

For the duration of the suspensions, therefore, Table I effectively reads:

Table I—Testing Requirements for Organic Toxic Pollutants by Industry Category

Industry category	GC/MS fraction 2				Volatile	Acid	Neutral	Pesticide	Adhesives and sealants	( 1)	( 1)	( 1)		Aluminum forming	( 1)	( 1)	( 1)		Auto and other laundries	( 1)	( 1)	( 1)	( 1)	Battery manufacturing	( 1)		( 1)		Coal mining					Coil coating	( 1)	( 1)	( 1)		Copper forming	( 1)	( 1)	( 1)		Electric and electronic compounds	( 1)	( 1)	( 1)	( 1)	Electroplating	( 1)	( 1)	( 1)		Explosives manufacturing		( 1)	( 1)		Foundries	( 1)	( 1)	( 1)		Gum and wood (all subparts except D and F)	( 1)	( 1)			Subpart D—tall oil rosin	( 1)	( 1)	( 1)		Subpart F—rosin-based derivatives	( 1)	( 1)	( 1)		Inorganic chemicals manufacturing	( 1)	( 1)	( 1)		Iron and steel manufacturing	( 1)	( 1)	( 1)		Leather tanning and finishing	( 1)	( 1)	( 1)		Mechanical products manufacturing	( 1)	( 1)	( 1)		Nonferrous metals manufacturing	( 1)	( 1)	( 1)	( 1)	Ore mining (applies to the base and precious metals/Subpart B)		( 1)			Organic chemicals manufacturing	( 1)	( 1)	( 1)	( 1)	Paint and ink formulation	( 1)	( 1)	( 1)		Pesticides	( 1)	( 1)	( 1)	( 1)	Petroleum refining	( 1)				Pharmaceutical preparations	( 1)	( 1)	( 1)		Photographic equipment and supplies	( 1)	( 1)	( 1)		Plastic and synthetic materials manufacturing	( 1)	( 1)	( 1)	( 1)	Plastic processing	( 1)				Porcelain enameling					Printing and publishing	( 1)	( 1)	( 1)	( 1)	Pulp and paperboard mills—see footnote 3					Rubber processing	( 1)	( 1)	( 1)		Soap and detergent manufacturing	( 1)	( 1)	( 1)		Steam electric power plants	( 1)	( 1)			Textile mills (Subpart C—Greige Mills are exempt from this table)	( 1)	( 1)	( 1)		Timber products processing	( 1)	( 1)	( 1)	( 1)

1 Testing required.

2 The pollutants in each fraction are listed in Item V-C.

3 Pulp and Paperboard Mills:

	Subpart 3	GS/MS fractions				VOA	Acid	Base/neutral	Pesticides		A	2	( 1)	2	( 1)		B	2	( 1)	2	2		C	2	( 1)	2	2		D	2	( 1)	2	2		E	( 1)	( 1)	2	( 1)		F	( 1)	( 1)	2	2		G	( 1)	( 1)	2	2		H	( 1)	( 1)	2	2		I	( 1)	( 1)	2	2		J	( 1)	( 1)	( 1)	2		K	( 1)	( 1)	2	2		L	( 1)	( 1)	2	2		M	( 1)	( 1)	2	2		N	( 1)	( 1)	2	2		O	( 1)	( 1)	2	2		P	( 1)	( 1)	2	2		Q	( 1)	( 1)	2	( 1)		R	2	( 1)	2	2		S	( 1)	( 1)	2	( 1)		T	( 1)	( 1)	2	( 1)		U	( 1)	( 1)	( 1)	2

1 Must test.

2 Do not test unless “reason to believe” it is discharged.

3 Subparts are defined in 40 CFR Part 430.

[48 FR 14153, Apr. 1, 1983, as amended at 49 FR 38050, Sept. 26, 1984; 50 FR 6940, Feb. 19, 1985]