- Table B-1 to Subpart B of Part 53—Performance Limit Specifications for Automated Methods

Link to an amendment published at 89 FR 16383, Mar. 6, 2024.
Performance
parameter
Units 1SO2O3CO NO2
(Std.
range)
Definitions and test
procedures
Std. range 3Lower range 2 3Std. range 3Lower range 2 3Std. range 3Lower range 2 31. Rangeppm0-0.5<0.50-0.5<0.50-50<500-0.5Sec. 53.23(a) 2. Noiseppm0.0010.00050.00250.0010.20.10.005Sec. 53.23(b) 3. Lower detectable limitppm0.0020.0010.0050.0020.40.20.010Sec. 53.23(c) 4. Interference equivalent Each interferentppm±0.0054 ±0.005±0.005±0.005±1.0±0.5±0.02Sec. 53.23(d) Total, all interferentsppm------0.04Sec. 53.23(d) 5. Zero drift, 12 and 24 hourppm±0.004±0.002±0.004±0.002±0.5±0.3±0.02Sec. 53.23(e) 6. Span drift, 24 hour 20% of upper range limitPercent------±20.0Sec. 53.23(e) 80% of upper range limitPercent±3.0±3.0±3.0±3.0±2.0±2.0±5.0Sec. 53.23(e) 7. Lag timeMinutes22222.02.020Sec. 53.23(e) 8. Rise timeMinutes22222.02.015Sec. 53.23(e) 9. Fall timeMinutes22222.02.015Sec. 53.23(e) 10. Precision 20% of upper range limit------Sec. 53.23(e) Percent 522221.01.04Sec. 53.23(e) 80% of upper range limit------Sec. 53.23(e) Percent 522221.01.06Sec. 53.23(e)
Sec. 53.23(e)

1 To convert from parts per million (ppm) to µg/m 3 at 25 °C and 760 mm Hg, multiply by M/0.02447, where M is the molecular weight of the gas. Percent means percent of the upper measurement range limit.

2 Tests for interference equivalent and lag time do not need to be repeated for any lower range provided the test for the standard range shows that the lower range specification (if applicable) is met for each of these test parameters.

3 For candidate analyzers having automatic or adaptive time constants or smoothing filters, describe their functional nature, and describe and conduct suitable tests to demonstrate their function aspects and verify that performances for calibration, noise, lag, rise, fall times, and precision are within specifications under all applicable conditions. For candidate analyzers with operator-selectable time constants or smoothing filters, conduct calibration, noise, lag, rise, fall times, and precision tests at the highest and lowest settings that are to be included in the FRM or FEM designation.

4 For nitric oxide interference for the SO2 UVF method, interference equivalent is ±0.0003 ppm for the lower range.

5 Standard deviation expressed as percent of the URL.

[80 FR 65460, Oct. 26, 2015]