- Table C-4 to Subpart C of Part 53—Test Specifications for PM 10, PM 2.5 and PM 10-2.5 Candidate Equivalent Methods

Link to an amendment published at 89 FR 16386, Mar. 6, 2024.
Specification PM 10PM 2.5PM 10-2.5Class I Class II Class III Class II Class III Acceptable concentration range (Rj), µg/m 315-3003-2003-2003-2003-2003-200 Minimum number of test sites212424 Minimum number of candidate method samplers or analyzers per site333 13 13 13 1Number of reference method samplers per site333 13 13 13 1Minimum number of acceptable sample sets per site for PM 10 methods: Rj <60 µg/m 33 Rj >60 µg/m 33 Total10 Minimum number of acceptable sample sets per site for PM 2.5 and PM 10-2.5 candidate equivalent methods: Rj <30 µg/m 3 for 24-hr or Rj <20 µg/m 3 for 48-hr samples3 Rj >30 µg/m 3 for 24-hr or Rj >20 µg/m 3 for 48-hr samples3 Each season1023232323 Total, each site102323 (46 for two-season sites)2323 (46 for two-season sites) Precision of replicate reference method measurements, PRj or RPRj, respectively; RP for Class II or III PM 2.5 or PM 10-2.5, maximum5 µg/m 3 or 7%2 µg/m 3 or 5%10% 210% 210% 210% 2Precision of PM 2.5 or PM 10-2.5 candidate method, CP, each site10% 215% 215% 215% 2Slope of regression relationship1 ±0.101 ±0.051 ±0.101 ±0.101 ±0.101 ±0.12 Intercept of regression relationship, µg/m 30 ±50 ±1Between: 13.55 − (15.05 × slope), but not less than −1.5; and 16.56 − (15.05 × slope), but not more than + 1.5Between: 15.05 − (17.32 × slope), but not less than −2.0; and 15.05 − (13.20 × slope), but not more than + 2.0Between: 62.05 − (70.5 × slope), but not less than −3.5; and 78.95 − (70.5 × slope), but not more than + 3.5Between: 70.50 − (82.93 × slope), but not less than −7.0; and 70.50 − (61.16 × slope), but not more than + 7.0 Correlation of reference method and candidate method measurements≥0.97≥0.97≥0.93—for CCV ≤0.4; ≥0.85 + 0.2 × CCV—for 0.4 ≤CCV ≤0.5; ≥0.95—for CCV ≥0.5

1 Some missing daily measurement values may be permitted; see test procedure.

2 Calculated as the root mean square over all measurement sets.

[72 FR 32203, June 12, 2007]