- Table A-1 to Subpart A of Part 98—Global Warming Potentials

Link to an amendment published at 89 FR 31894, Apr. 25, 2024.

[100-Year Time Horizon]

Name CAS No. Chemical formula Global
warming
potential
(100 yr.)
Chemical-Specific GWPsCarbon dioxide124-38-9CO21 Methane74-82-8CH4a 25 Nitrous oxide10024-97-2N2Oa 298 Fully Fluorinated GHGsSulfur hexafluoride2551-62-4SF6a 22,800 Trifluoromethyl sulphur pentafluoride373-80-8SF5CF317,700 Nitrogen trifluoride7783-54-2NF317,200 PFC-14 (Perfluoromethane)75-73-0CF4a 7,390 PFC-116 (Perfluoroethane)76-16-4C2F6a 12,200 PFC-218 (Perfluoropropane)76-19-7C3F8a 8,830 Perfluorocyclopropane931-91-9C-C3F617,340 PFC-3-1-10 (Perfluorobutane)355-25-9C4F10a 8,860 PFC-318 (Perfluorocyclobutane)115-25-3C-C4F8a 10,300 PFC-4-1-12 (Perfluoropentane)678-26-2C5F12a 9,160 PFC-5-1-14 (Perfluorohexane, FC-72)355-42-0C6F14a 9,300 PFC-6-1-12335-57-9C7F16; CF3(CF2)5CF3b 7,820 PFC-7-1-18307-34-6C8F18; CF3(CF2)6CF3b 7,620 PFC-9-1-18306-94-5C10F187,500 PFPMIE (HT-70)NACF3OCF(CF3)CF2OCF2OCF310,300 Perfluorodecalin (cis)60433-11-6Z-C10F18b 7,236 Perfluorodecalin (trans)60433-12-7E-C10F18b 6,288 Saturated Hydrofluorocarbons (HFCs) With Two or Fewer Carbon-Hydrogen BondsHFC-2375-46-7CHF3a 14,800 HFC-3275-10-5CH2F2a 675 HFC-125354-33-6C2HF5a 3,500 HFC-134359-35-3C2H2F4a 1,100 HFC-134a811-97-2CH2FCF3a 1,430 HFC-227ca2252-84-8CF3CF2CHF2b 2640 HFC-227ea431-89-0C3HF7a 3,220 HFC-236cb677-56-5CH2FCF2CF31,340 HFC-236ea431-63-0CHF2CHFCF31,370 HFC-236fa690-39-1C3H2F6a 9,810 HFC-329p375-17-7CHF2CF2CF2CF3b 2360 HFC-43-10mee138495-42-8CF3CFHCFHCF2CF3a 1,640 Saturated Hydrofluorocarbons (HFCs) With Three or More Carbon-Hydrogen BondsHFC-41593-53-3CH3Fa 92 HFC-143430-66-0C2H3F3a 353 HFC-143a420-46-2C2H3F3a 4,470 HFC-152624-72-6CH2FCH2F53 HFC-152a75-37-6CH3CHF2a 124 HFC-161353-36-6CH3CH2F12 HFC-245ca679-86-7C3H3F5a 693 HFC-245cb1814-88-6CF3CF2CH3b 4620 HFC-245ea24270-66-4CHF2CHFCHF2b 235 HFC-245eb431-31-2CH2FCHFCF3b 290 HFC-245fa460-73-1CHF2CH2CF31,030 HFC-263fb421-07-8CH3CH2CF3b 76 HFC-272ca420-45-1CH3CF2CH3b 144 HFC-365mfc406-58-6CH3CF2CH2CF3794 Saturated Hydrofluoroethers (HFEs) and Hydrochlorofluoroethers (HCFEs) With One Carbon-Hydrogen BondHFE-1253822-68-2CHF2OCF314,900 HFE-227ea2356-62-9CF3CHFOCF31,540 HFE-329mcc2134769-21-4CF3CF2OCF2CHF2919 HFE-329me3428454-68-6CF3CFHCF2OCF3b 4,550 1,1,1,2,2,3,3-Heptafluoro-3-(1,2,2,2-tetrafluoroethoxy)-propane3330-15-2CF3CF2CF2OCHFCF3b 6,490 Saturated HFEs and HCFEs With Two Carbon-Hydrogen BondsHFE-134 (HG-00)1691-17-4CHF2OCHF26,320 HFE-236ca32778-11-3CHF2OCF2CHF2b 4,240 HFE-236ca12 (HG-10)78522-47-1CHF2OCF2OCHF22,800 HFE-236ea2 (Desflurane)57041-67-5CHF2OCHFCF3989 HFE-236fa20193-67-3CF3CH2OCF3487 HFE-338mcf2156053-88-2CF3CF2OCH2CF3552 HFE-338mmz126103-08-2CHF2OCH(CF3)2380 HFE-338pcc13 (HG-01)188690-78-0CHF2OCF2CF2OCHF21,500 HFE-43-10pccc (H-Galden 1040x, HG-11)E1730133CHF2OCF2OC2F4OCHF21,870 HCFE-235ca2 (Enflurane)13838-16-9CHF2OCF2CHFClb 583 HCFE-235da2 (Isoflurane)26675-46-7CHF2OCHClCF3350 HG-02205367-61-9HF2C-(OCF2CF2)2-OCF2Hb 3,825 HG-03173350-37-3HF2C-(OCF2CF2)3-OCF2Hb 3,670 HG-20249932-25-0HF2C-(OCF2)2-OCF2Hb 5,300 HG-21249932-26-1HF2C-OCF2CF2OCF2OCF2O-CF2Hb 3,890 HG-30188690-77-9HF2C-(OCF2)3-OCF2Hb 7,330 1,1,3,3,4,4,6,6,7,7,9,9,10,10,12,12,13,13,15,15-eicosafluoro-2,5,8,11,14-Pentaoxapentadecane173350-38-4HCF2O(CF2CF2O)4CF2Hb 3,630 1,1,2-Trifluoro-2-(trifluoromethoxy)-ethane84011-06-3CHF2CHFOCF3b 1,240 Trifluoro(fluoromethoxy)methane2261-01-0CH2FOCF3b 751 Saturated HFEs and HCFEs With Three or More Carbon-Hydrogen BondsHFE-143a421-14-7CH3OCF3756 HFE-245cb222410-44-2CH3OCF2CF3708 HFE-245fa184011-15-4CHF2CH2OCF3286 HFE-245fa21885-48-9CHF2OCH2CF3659 HFE-254cb2425-88-7CH3OCF2CHF2359 HFE-263fb2460-43-5CF3CH2OCH311 HFE-263m1; R-E-143a690-22-2CF3OCH2CH3b 29 HFE-347mcc3 (HFE-7000)375-03-1CH3OCF2CF2CF3575 HFE-347mcf2171182-95-9CF3CF2OCH2CHF2374 HFE-347mmy122052-84-2CH3OCF(CF3)2343 HFE-347mmz1 (Sevoflurane)28523-86-6(CF3)2CHOCH2Fc 216 HFE-347pcf2406-78-0CHF2CF2OCH2CF3580 HFE-356mec3382-34-3CH3OCF2CHFCF3101 HFE-356mff2333-36-8CF3CH2OCH2CF3b 17 HFE-356mmz113171-18-1(CF3)2CHOCH327 HFE-356pcc3160620-20-2CH3OCF2CF2CHF2110 HFE-356pcf250807-77-7CHF2CH2OCF2CHF2265 HFE-356pcf335042-99-0CHF2OCH2CF2CHF2502 HFE-365mcf222052-81-9CF3CF2OCH2CH3b 58 HFE-365mcf3378-16-5CF3CF2CH2OCH311 HFE-374pc2512-51-6CH3CH2OCF2CHF2557 HFE-449s1 (HFE-7100) Chemical blend163702-07-6C4F9OCH3297 163702-08-7(CF3)2CFCF2OCH3HFE-569sf2 (HFE-7200) Chemical blend163702-05-4C4F9OC2H559 163702-06-5(CF3)2CFCF2OC2H5HG'-0173287-23-7CH3OCF2CF2OCH3b 222 HG'-02485399-46-0CH3O(CF2CF2O)2CH3b 236 HG'-03485399-48-2CH3O(CF2CF2O)3CH3b 221 Difluoro(methoxy)methane359-15-9CH3OCHF2b 144 2-Chloro-1,1,2-trifluoro-1-methoxyethane425-87-6CH3OCF2CHFClb 122 1-Ethoxy-1,1,2,2,3,3,3-heptafluoropropane22052-86-4CF3CF2CF2OCH2CH3b 61 2-Ethoxy-3,3,4,4,5-pentafluorotetrahydro-2,5-bis[1,2,2,2-tetrafluoro-1-(trifluoromethyl)ethyl]-furan920979-28-8C12H5F19O2b 56 1-Ethoxy-1,1,2,3,3,3-hexafluoropropane380-34-7CF3CHFCF2OCH2CH3b 23 Fluoro(methoxy)methane460-22-0CH3OCH2Fb 13 1,1,2,2-Tetrafluoro-3-methoxy-propane; Methyl 2,2,3,3-tetrafluoropropyl ether60598-17-6CHF2CF2CH2OCH3b 0.5 1,1,2,2-Tetrafluoro-1-(fluoromethoxy)ethane37031-31-5CH2FOCF2CF2Hb 871 Difluoro(fluoromethoxy)methane461-63-2CH2FOCHF2b 617 Fluoro(fluoromethoxy)methane462-51-1CH2FOCH2Fb 130 Fluorinated FormatesTrifluoromethyl formate85358-65-2HCOOCF3b 588 Perfluoroethyl formate313064-40-3HCOOCF2CF3b 580 1,2,2,2-Tetrafluoroethyl formate481631-19-0HCOOCHFCF3b 470 Perfluorobutyl formate197218-56-7HCOOCF2CF2CF2CF3b 392 Perfluoropropyl formate271257-42-2HCOOCF2CF2CF3b 376 1,1,1,3,3,3-Hexafluoropropan-2-yl formate856766-70-6HCOOCH(CF3)2b 333 2,2,2-Trifluoroethyl formate32042-38-9HCOOCH2CF3b 33 3,3,3-Trifluoropropyl formate1344118-09-7HCOOCH2CH2CF3b 17 Fluorinated AcetatesMethyl 2,2,2-trifluoroacetate431-47-0CF3COOCH3b 52 1,1-Difluoroethyl 2,2,2-trifluoroacetate1344118-13-3CF3COOCF2CH3b 31 Difluoromethyl 2,2,2-trifluoroacetate2024-86-4CF3COOCHF2b 27 2,2,2-Trifluoroethyl 2,2,2-trifluoroacetate407-38-5CF3COOCH2CF3b 7 Methyl 2,2-difluoroacetate433-53-4HCF2COOCH3b 3 Perfluoroethyl acetate343269-97-6CH3COOCF2CF3b 2.1 Trifluoromethyl acetate74123-20-9CH3COOCF3b 2.0 Perfluoropropyl acetate1344118-10-0CH3COOCF2CF2CF3b 1.8 Perfluorobutyl acetate209597-28-4CH3COOCF2CF2CF2CF3b 1.6 Ethyl 2,2,2-trifluoroacetate383-63-1CF3COOCH2CH3b 1.3 CarbonofluoridatesMethyl carbonofluoridate1538-06-3FCOOCH3b 95 1,1-Difluoroethyl carbonofluoridate1344118-11-1FCOOCF2CH3b 27 Fluorinated Alcohols Other Than Fluorotelomer AlcoholsBis(trifluoromethyl)-methanol920-66-1(CF3)2CHOH195 (Octafluorotetramethy-lene) hydroxymethyl groupNAX-(CF2)4CH(OH)-X73 2,2,3,3,3-Pentafluoropropanol422-05-9CF3CF2CH2OH42 2,2,3,3,4,4,4-Heptafluorobutan-1-ol375-01-9C3F7CH2OHb 25 2,2,2-Trifluoroethanol75-89-8CF3CH2OHb 20 2,2,3,4,4,4-Hexafluoro-1-butanol382-31-0CF3CHFCF2CH2OHb 17 2,2,3,3-Tetrafluoro-1-propanol76-37-9CHF2CF2CH2OHb 13 2,2-Difluoroethanol359-13-7CHF2CH2OHb 3 2-Fluoroethanol371-62-0CH2FCH2OHb 1.1 4,4,4-Trifluorobutan-1-ol461-18-7CF3(CH2)2CH2OHb 0.05 Unsaturated Perfluorocarbons (PFCs)PFC-1114; TFE116-14-3CF2 = CF2; C2F4b 0.004 PFC-1216; Dyneon HFP116-15-4C3F6; CF3CF = CF2b 0.05 PFC C-1418559-40-0c-C5F8b 1.97 Perfluorobut-2-ene360-89-4CF3CF = CFCF3b 1.82 Perfluorobut-1-ene357-26-6CF3CF2CF = CF2b 0.10 Perfluorobuta-1,3-diene685-63-2CF2 = CFCF = CF2b 0.003 Unsaturated Hydrofluorocarbons (HFCs) and Hydrochlorofluorocarbons (HCFCs)HFC-1132a; VF275-38-7C2H2F2 , CF2 = CH2b 0.04 HFC-1141; VF75-02-5C2H3F, CH2 = CHFb 0.02 (E)-HFC-1225ye5595-10-8CF3CF = CHF(E)b 0.06 (Z)-HFC-1225ye5528-43-8CF3CF = CHF(Z)b 0.22 Solstice 1233zd(E)102687-65-0C3H2ClF3; CHCl = CHCF3b 1.34 HFC-1234yf; HFO-1234yf754-12-1C3H2F4; CF3CF = CH2b 0.31 HFC-1234ze(E)1645-83-6C3H2F4; trans-CF3CH = CHFb 0.97 HFC-1234ze(Z)29118-25-0C3H2F4; cis-CF3CH = CHF; CF3CH = CHFb 0.29 HFC-1243zf; TFP677-21-4C3H3F3, CF3CH = CH2b 0.12 (Z)-HFC-1336692-49-9CF3CH = CHCF3(Z)b 1.58 HFC-1345zfc374-27-6C2F5CH = CH2b 0.09 Capstone 42-U19430-93-4C6H3F9, CF3(CF2)3CH = CH2b 0.16 Capstone 62-U25291-17-2C8H3F13, CF3(CF2)5CH = CH2b 0.11 Capstone 82-U21652-58-4C10H3F17, CF3(CF2)7CH = CH2b 0.09 Unsaturated Halogenated EthersPMVE; HFE-2161187-93-5CF3OCF = CF2b 0.17 Fluoroxene406-90-6CF3CH2OCH = CH2b 0.05 Fluorinated Aldehydes3,3,3-Trifluoro-propanal460-40-2CF3CH2CHOb 0.01 Fluorinated KetonesNovec 1230 (perfluoro (2-methyl-3-pentanone))756-13-8CF3CF2C(O)CF (CF3)2b 0.1 Fluorotelomer Alcohols3,3,4,4,5,5,6,6,7,7,7-Undecafluoroheptan-1-ol185689-57-0CF3(CF2)4CH2CH2OHb 0.43 3,3,3-Trifluoropropan-1-ol2240-88-2CF3CH2CH2OHb 0.35 3,3,4,4,5,5,6,6,7,7,8,8,9,9,9-Pentadecafluorononan-1-ol755-02-2CF3(CF2)6CH2CH2OHb 0.33 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-Nonadecafluoroundecan-1-ol87017-97-8CF3(CF2)8CH2CH2OHb 0.19 Fluorinated GHGs With Carbon-Iodine Bond(s)Trifluoroiodomethane2314-97-8CF3Ib 0.4 Other Fluorinated CompoundsDibromodifluoromethane (Halon 1202)75-61-6CBR2F2b 231 2-Bromo-2-chloro-1,1,1-trifluoroethane (Halon-2311/Halothane)151-67-7CHBrClCF3b 41
Fluorinated GHG Group dGlobal
warming
potential
(100 yr.)
Default GWPs for Compounds for Which Chemical-Specific GWPs Are Not Listed AboveFully fluorinated GHGs10,000 Saturated hydrofluorocarbons (HFCs) with 2 or fewer carbon-hydrogen bonds3,700 Saturated HFCs with 3 or more carbon-hydrogen bonds930 Saturated hydrofluoroethers (HFEs) and hydrochlorofluoroethers (HCFEs) with 1 carbon-hydrogen bond5,700 Saturated HFEs and HCFEs with 2 carbon-hydrogen bonds2,600 Saturated HFEs and HCFEs with 3 or more carbon-hydrogen bonds270 Fluorinated formates350 Fluorinated acetates, carbonofluoridates, and fluorinated alcohols other than fluorotelomer alcohols30 Unsaturated perfluorocarbons (PFCs), unsaturated HFCs, unsaturated hydrochlorofluorocarbons (HCFCs), unsaturated halogenated ethers, unsaturated halogenated esters, fluorinated aldehydes, and fluorinated ketones1 Fluorotelomer alcohols1 Fluorinated GHGs with carbon-iodine bond(s)1 Other fluorinated GHGs2,000

a The GWP for this compound was updated in the final rule published on November 29, 2013 [78 FR 71904] and effective on January 1, 2014.

b This compound was added to Table A-1 in the final rule published on December 11, 2014, and effective on January 1, 2015.

c The GWP for this compound was updated in the final rule published on December 11, 2014, and effective on January 1, 2015 .

d For electronics manufacturing (as defined in § 98.90), the term “fluorinated GHGs” in the definition of each fluorinated GHG group in § 98.6 shall include fluorinated heat transfer fluids (as defined in § 98.98), whether or not they are also fluorinated GHGs.

[79 FR 73779, Dec. 11, 2014]